Assessment and influence of operational parameters on the TiO(2) photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination
文献类型：期刊论文
| 作者 | Zhang, TY; Oyama, T; Horikoshi, S; Zhao, JC; Hidaka, H; Serpone, N |
| 刊名 | SOLAR ENERGY
 |
| 出版日期 | 2001 |
| 卷号 | 71期号:5页码:305-313 |
| ISSN号 | 0038-092X |
| 英文摘要 | Sodium benzene sulfonate (BS) was decomposed in aqueous TiO(2) dispersions under highly concentrated solar light illumination to examine the photocatalytic characteristics of a parabolic round concentrator (PRC) reactor to degrade the pollutant without visible light absorption. The effects of such operational parameters as initial concentration, volume of the aqueous BS solution, oxygen purging, and TiO(2) loading on the kinetics of decomposition of BS were investigated. An effective photodegradation necessitates a suitable combination of initial volume and concentration of BS solution. Relative to atmospheric air, oxygen purging significantly accelerates the degradation process at high initial concentrations of BS (0.40 mM or 1.0 mM). Optimal TiO(2) loading was 9 g l(-1), greater than previously reported. Elimination of TOC (total organic carbon) followed pseudo first-order kinetics in the initial stages of the photodegradation process. The relative photonic efficiency for the photodegradation of BS is zeta (rel) = 1.0. (C) 2001 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000171425400003 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77245]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hidaka, H |
| 作者单位 | 1.Iwaki Meisei Univ, Frontier Res Ctr Global Environm Protect, Hino, Tokyo 1918506, Japan 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Photochem, Beijing 100080, Peoples R China 3.Concordia Univ, Dept Chem & Biochem, Montreal, PQ H3G 1M8, Canada 4.Tianjin Univ, Coll Chem Engn & Technol, Dept Appl Chem, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, TY,Oyama, T,Horikoshi, S,et al. Assessment and influence of operational parameters on the TiO(2) photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination[J]. SOLAR ENERGY,2001,71(5):305-313. |
| APA | Zhang, TY,Oyama, T,Horikoshi, S,Zhao, JC,Hidaka, H,&Serpone, N.(2001).Assessment and influence of operational parameters on the TiO(2) photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination.SOLAR ENERGY,71(5),305-313. |
| MLA | Zhang, TY,et al."Assessment and influence of operational parameters on the TiO(2) photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination".SOLAR ENERGY 71.5(2001):305-313. |
入库方式： OAI收割
来源：化学研究所
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