Using energy transfer to probe solvent dependent conformational changes in a D-A podand
文献类型：期刊论文
| 作者 | Jiang, H; Xu, HJ |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2001-12-01 |
| 卷号 | 17期号:12页码:1092-1096 |
| 关键词 | Energy Transfer Conformational Change Podand Dyad Naphthalene Anthracene |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20011207 |
| 英文摘要 | A podand carrying terminal naphthalene as energy donor and anthracene as energy acceptor groups (DSA) has been synthesized. Absorption spectroscopy showed that there was no intramolecular interaction between the two chromophores in ground state. Selective excitation of the naphthalene moiety a decrease in the naphthalene fluorescence is observed accompanied by an increase in the anthracene emission. The results indicate that singlet-singlet energy transfer from naphthalene to anthracene occurs. It is demonstrated that the efficiency of energy transfer is influenced by the solvent polarity attributed to the differences in the conformation about the central C - C bond of the - OCH2CH2O - unit which is predominantly trans in low-polarity solvent such as benzene but predominantly gauche in high-polarity solvent such as acetonitrile. This in turn is expected to lead to variations of the naphthalene-anthracene separation that effects energy transfer efficiency. It is concluded that energy transfer can be used as a diagnostic tool to probe solvent-specific conformational properties of a D-A system with a flexible bridging ligand. |
| 语种 | 英语 |
| WOS记录号 | WOS:000172839700007 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77269]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, HJ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, H,Xu, HJ. Using energy transfer to probe solvent dependent conformational changes in a D-A podand[J]. ACTA PHYSICO-CHIMICA SINICA,2001,17(12):1092-1096. |
| APA | Jiang, H,&Xu, HJ.(2001).Using energy transfer to probe solvent dependent conformational changes in a D-A podand.ACTA PHYSICO-CHIMICA SINICA,17(12),1092-1096. |
| MLA | Jiang, H,et al."Using energy transfer to probe solvent dependent conformational changes in a D-A podand".ACTA PHYSICO-CHIMICA SINICA 17.12(2001):1092-1096. |
入库方式： OAI收割
来源：化学研究所
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