中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Nonisothermal crystallization kinetics: poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymer and poly(ethylene oxide) homopolymer

文献类型:期刊论文

作者Kong, XH; Yang, XN; Li, G; Zhao, XG; Zhou, EL; Ma, DZ
刊名EUROPEAN POLYMER JOURNAL
出版日期2001-09-01
卷号37期号:9页码:1855-1862
关键词Poly(Ethylene Terephthalate)-Poly(Ethylene Oxide) coPolymer Poly(Ethylene Oxide) Nonisothermal Crystallization Crystallization Kinetics Ozawa Equation Secondary Crystallization
ISSN号0014-3057
英文摘要The nonisothermal crystallization behavior of polyethylene oxide (PEO) in poly(ethylene terephthalate)poly(ethylene oxide) (PETPEO) segmented copolymer and PEO homopolymer has been studied by means of differential scanning calorimetry, as well as transmission electron microscope. The kinetics of PEO in copolymer and PEO homopolymer under nonisothermal crystallization condition has been analyzed by Ozawa equation. The results show that Ozawa equation only describes the crystallization behavior of PEO-6000 homopolymer successfully, but fails to describe the whole crystallization process of PEO in copolymer because the secondary crystallization in the later stage could not be neglected. Due to the constraint of PET segments imposed on the PEO segments, a distinct two stage of crystallization of PEO in copolymer has been investigated by using Avrami equation modified by Jeziorny to deal with the nonisothermal crystallization data. In the case of PEO-6000 homopolymer, good linear relation for the whole crystallization process is obtained owing to the secondary crystallization does not occur under our experimental condition. (C) 2001 Elsevier Science Ltd. All rights reserved.
语种英语
WOS记录号WOS:000169806400019
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/77297]  
专题中国科学院化学研究所
通讯作者Li, G
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
推荐引用方式
GB/T 7714
Kong, XH,Yang, XN,Li, G,et al. Nonisothermal crystallization kinetics: poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymer and poly(ethylene oxide) homopolymer[J]. EUROPEAN POLYMER JOURNAL,2001,37(9):1855-1862.
APA Kong, XH,Yang, XN,Li, G,Zhao, XG,Zhou, EL,&Ma, DZ.(2001).Nonisothermal crystallization kinetics: poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymer and poly(ethylene oxide) homopolymer.EUROPEAN POLYMER JOURNAL,37(9),1855-1862.
MLA Kong, XH,et al."Nonisothermal crystallization kinetics: poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymer and poly(ethylene oxide) homopolymer".EUROPEAN POLYMER JOURNAL 37.9(2001):1855-1862.

入库方式: OAI收割

来源:化学研究所

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