Investigations on the hydrolytic stability of polyphenyl-1, 3, 5-triazine in water at high temperature
文献类型：期刊论文
| 作者 | Yi, XB; Lu, FC; Wu, GS |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2001 |
| 卷号 | 59期号:10页码:1803-1808 |
| 关键词 | Heat- And Hydrolysis-resistant Polymer Hydrolytic Stability Activation Energy Polyphenyl-1 3 5-triazine |
| ISSN号 | 0567-7351 |
| 英文摘要 | Hydrolysis of polyphenyl-1, 3, 5-triazine and its model compound were conducted in water at 250 degreesC/3. 97 MPa. The results showed that polyphenyl-1, 3, 5-triazine has outstanding heat and hydrolytic stability because no notable changes were observed on the IR spectra. The major hydrolysates from the polymer and model compound were aromatic carboxylic acids, which characterized by high performance liquid chromatography, high performance capillary electrophoresis, and liquid chromatography-mass spectrometer. Hydrolytic mechanisms were also suggested on the basis of the experimental observations. The high activation energy for the rate-dominative step predicted by the semiempirical quantum chemistry method, PM3, well expounded the excellent hydrolytic stability of polyphenyl-1, 3, 5-triazine. |
| 语种 | 英语 |
| WOS记录号 | WOS:000171884400049 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77299]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yi, XB |
| 作者单位 | 1.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, XB,Lu, FC,Wu, GS. Investigations on the hydrolytic stability of polyphenyl-1, 3, 5-triazine in water at high temperature[J]. ACTA CHIMICA SINICA,2001,59(10):1803-1808. |
| APA | Yi, XB,Lu, FC,&Wu, GS.(2001).Investigations on the hydrolytic stability of polyphenyl-1, 3, 5-triazine in water at high temperature.ACTA CHIMICA SINICA,59(10),1803-1808. |
| MLA | Yi, XB,et al."Investigations on the hydrolytic stability of polyphenyl-1, 3, 5-triazine in water at high temperature".ACTA CHIMICA SINICA 59.10(2001):1803-1808. |
入库方式： OAI收割
来源：化学研究所
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