Transition metal acetylide catalysts for polymerization of alkynes 1. Effect of ligands on catalytic activity of nickel complexes
文献类型：期刊论文
| 作者 | Zhan, XW; Yang, MJ |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2001-03-28 |
| 卷号 | 169期号:1-2页码:27-31 |
| 关键词 | Transition Metal Acetylide Catalyst Alkyne Polymerization |
| ISSN号 | 1381-1169 |
| 英文摘要 | The catalytic activity of a series of nickel acetylides and chlorides containing different phosphine and alkynyl ligands: NiL2(C equivalent to CR)(2); NiL2(C equivalent to CR)Cl and NiL2Cl2 (L-2 = (PPh3)(2), (PBu3)(2) and Ph2PCH2CH2PPh2; R = p-C6H4C equivalent to CH, C6H5. H, CH2OH and CH2OCOCH3), towards p-diethynylbenzene polymerization is compared. The catalytic property of these acetylides is related to chlorine, phosphines and alkynyl ligands bonded to the metal atoms. The polarity, steric hindrance and electron-donating ability of ligands are main factors influencing the catalytic activity of these complexes. Nickel acetylides were found to be novel efficient initiating systems for the alkyne polymerization. The polymerization proceeds under mild conditions to give soluble rr-conjugated polymers with weight average molecular weights as high as 4.8 x 10(4) in yields as high as 95%, (C) 2001 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000167803100004 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77387]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, XW |
| 作者单位 | 1.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhan, XW,Yang, MJ. Transition metal acetylide catalysts for polymerization of alkynes 1. Effect of ligands on catalytic activity of nickel complexes[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,169(1-2):27-31. |
| APA | Zhan, XW,&Yang, MJ.(2001).Transition metal acetylide catalysts for polymerization of alkynes 1. Effect of ligands on catalytic activity of nickel complexes.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,169(1-2),27-31. |
| MLA | Zhan, XW,et al."Transition metal acetylide catalysts for polymerization of alkynes 1. Effect of ligands on catalytic activity of nickel complexes".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 169.1-2(2001):27-31. |
入库方式： OAI收割
来源：化学研究所
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