中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)

文献类型:期刊论文

作者Yuan, ZH; Shen, DY; Qian, RY
刊名CHINESE JOURNAL OF POLYMER SCIENCE
出版日期2001-07-01
卷号19期号:4页码:399-405
关键词Pre-yield Deformation Pet Uniaxial Drawing Non-hooke Deformation Viscoelasticity Stress Induced Rubbery Deformation
ISSN号0256-7679
英文摘要Viscoelastic behavior of the non-Hooke deformation of amorphous PET film before yield was investigated in the temperature region 74-80.5 degreesC around the glass transition temperature. The film specimen was drawn to yield point followed by unloading to zero stress, then the residual deformation was held constant; while the subsequent evolution of the stress was recorded. An induction period was found in the course of stress evolution followed by a stress step-increase. The induction period decreases with increasing drawing temperature with an activation energy of 1.10 MJ/mol.K, which is attributed to the time needed for the relaxation of rubbery deformation through cooperative internal rotations. At temperatures lower than 74 degreesC, there is no stress increase or the induction period becomes too long to be observed. Thus the nature of anelasticity in the non-Hooke region before yielding is attributed to stress induced rubbery deformation. The experimental results are interpreted in terms of Perez' theological model of a series connected Hooks spring and a Voigt element consisting of a parallel connected elastic spring and a dashpot.
语种英语
WOS记录号WOS:000169782300009
出版者SPRINGER-VERLAG BERLIN
源URL[http://ir.iccas.ac.cn/handle/121111/77413]  
专题中国科学院化学研究所
通讯作者Qian, RY
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Polymer Phys Lab, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Yuan, ZH,Shen, DY,Qian, RY. Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2001,19(4):399-405.
APA Yuan, ZH,Shen, DY,&Qian, RY.(2001).Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate).CHINESE JOURNAL OF POLYMER SCIENCE,19(4),399-405.
MLA Yuan, ZH,et al."Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)".CHINESE JOURNAL OF POLYMER SCIENCE 19.4(2001):399-405.

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来源:化学研究所

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