Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)
文献类型:期刊论文
作者 | Yuan, ZH; Shen, DY; Qian, RY |
刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
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出版日期 | 2001-07-01 |
卷号 | 19期号:4页码:399-405 |
关键词 | Pre-yield Deformation Pet Uniaxial Drawing Non-hooke Deformation Viscoelasticity Stress Induced Rubbery Deformation |
ISSN号 | 0256-7679 |
英文摘要 | Viscoelastic behavior of the non-Hooke deformation of amorphous PET film before yield was investigated in the temperature region 74-80.5 degreesC around the glass transition temperature. The film specimen was drawn to yield point followed by unloading to zero stress, then the residual deformation was held constant; while the subsequent evolution of the stress was recorded. An induction period was found in the course of stress evolution followed by a stress step-increase. The induction period decreases with increasing drawing temperature with an activation energy of 1.10 MJ/mol.K, which is attributed to the time needed for the relaxation of rubbery deformation through cooperative internal rotations. At temperatures lower than 74 degreesC, there is no stress increase or the induction period becomes too long to be observed. Thus the nature of anelasticity in the non-Hooke region before yielding is attributed to stress induced rubbery deformation. The experimental results are interpreted in terms of Perez' theological model of a series connected Hooks spring and a Voigt element consisting of a parallel connected elastic spring and a dashpot. |
语种 | 英语 |
WOS记录号 | WOS:000169782300009 |
出版者 | SPRINGER-VERLAG BERLIN |
源URL | [http://ir.iccas.ac.cn/handle/121111/77413] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Qian, RY |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Polymer Phys Lab, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Yuan, ZH,Shen, DY,Qian, RY. Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2001,19(4):399-405. |
APA | Yuan, ZH,Shen, DY,&Qian, RY.(2001).Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate).CHINESE JOURNAL OF POLYMER SCIENCE,19(4),399-405. |
MLA | Yuan, ZH,et al."Viscoelastic behavior of the non-Hooke deformation before yielding in uniaxial drawing of amorphous poly(ethylene terephthalate)".CHINESE JOURNAL OF POLYMER SCIENCE 19.4(2001):399-405. |
入库方式: OAI收割
来源:化学研究所
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