Monolayers of novel calix[4]arene derivative and its palladium(II) complexes formed at the air-water interface
文献类型：期刊论文
| 作者 | He, WJ; Liu, F; Ye, ZF; Zhang, Y; Guo, ZJ; Zhu, LG; Zhai, XH; Li, JB |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2001-02-20 |
| 卷号 | 17期号:4页码:1143-1149 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/la001090o |
| 英文摘要 | 5,11,17,23-Tetra-tert-butyl-25,27-di{[(2'-amino-4'-methylthio)butyryl]aminoethoxy}-26,28-dihydroxycalix[4]- arene (L) and its mono- and binuclear palladium(II) complexes (PdLCl2 and Pd2LCl4) were synthesized. Their monolayers at the air-water interface were investigated by film balance measurements (compression/expansion experiments, area relaxation experiments, viscosity measurements) and Brewster angle microscopy. The monolayer oft is inclined to form domains and multilayers, while the monolayer of PdLCl2 demonstrates good reversibility and high collapse pressure. The monolayer formed by Pd2LCl4 exhibits extraordinary cohesiveness, stability, and robustness. Its extraordinary properties are likely due to the intermolecular cross-linkage of precursor complex of Pd2LCl4 via strong chloride bridges. This provides an example of improving mechanical, properties of film through intermolecular metal complexing. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000167064600027 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77417]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, LG |
| 作者单位 | 1.Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Colloid & Interface Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, WJ,Liu, F,Ye, ZF,et al. Monolayers of novel calix[4]arene derivative and its palladium(II) complexes formed at the air-water interface[J]. LANGMUIR,2001,17(4):1143-1149. |
| APA | He, WJ.,Liu, F.,Ye, ZF.,Zhang, Y.,Guo, ZJ.,...&Li, JB.(2001).Monolayers of novel calix[4]arene derivative and its palladium(II) complexes formed at the air-water interface.LANGMUIR,17(4),1143-1149. |
| MLA | He, WJ,et al."Monolayers of novel calix[4]arene derivative and its palladium(II) complexes formed at the air-water interface".LANGMUIR 17.4(2001):1143-1149. |
入库方式： OAI收割
来源：化学研究所
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