Nanocomposite system of N-methylstilbazoliums intercalated into lamellar FePS3
文献类型：期刊论文
| 作者 | Chen, XG; Yang, CL; Qin, JG; Inokuchi, M; Fujii, Y; Kinoshita, M; Yakushi, K; Ichimura, K; Liu, YQ |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2001-03-15 |
| 卷号 | 121期号:1-3页码:1307-1308 |
| 关键词 | X-ray Powder Diffraction Organic/inorganic Interfaces Magnetic Measurement Magnetic Phase Transition |
| ISSN号 | 0379-6779 |
| 英文摘要 | A new series of inorganic-organic hybrid materials, 2 ' -R-1-4 ' -R-2-N-methylstilbazoliums (a, R-1 = R-2 = MeO; b, R-1 = R-2 = Cl; c, R-1 = R-2 = H: d, R-1 = H, R-2 = MeO; e, R-1 = H, R-2 = Cl) intercalated into lamellar FePS3, were synthesized through ion-exchange process. Compared with FePS3(d = 6.42 Angstrom), the lattice spacing expansion (Deltad) of 14.6 Angstrom for Intercalate a, 13.2 Angstrom for Intercalate b and 5.7 similar to 6.0 Angstrom for Intercalate c, d and e indicated that the molecular ring planes of the guests are perpendicular to the layers of the host. Among them the lattice spacing of 21.02 Angstrom for Intercalate a is the largest for all FePS3 intercalates reported. Their magnetic properties were studied, all of which exhibited the similar antiferromagnetic properties with Neel temperature at around 80 K. It seems that the lattice spacing expansion and the electron-effect of substitution group of the guest have little influence on the magnetic properties for these intercalates. |
| 语种 | 英语 |
| WOS记录号 | WOS:000168831200100 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Qin, JG |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Sci Univ Tokyo, Dept Mat Sci & Engn, Yamaguchi 7560884, Japan 3.Inst Mol Sci, Okazaki, Aichi 444, Japan 4.Kumamoto Univ, Dept Chem, Kumamoto 860, Japan 5.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, XG,Yang, CL,Qin, JG,et al. Nanocomposite system of N-methylstilbazoliums intercalated into lamellar FePS3[J]. SYNTHETIC METALS,2001,121(1-3):1307-1308. |
| APA | Chen, XG.,Yang, CL.,Qin, JG.,Inokuchi, M.,Fujii, Y.,...&Liu, YQ.(2001).Nanocomposite system of N-methylstilbazoliums intercalated into lamellar FePS3.SYNTHETIC METALS,121(1-3),1307-1308. |
| MLA | Chen, XG,et al."Nanocomposite system of N-methylstilbazoliums intercalated into lamellar FePS3".SYNTHETIC METALS 121.1-3(2001):1307-1308. |
入库方式： OAI收割
来源：化学研究所
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