中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Langmuir monolayer of hypocrellins and their amino substituted derivatives at the air/water interface: Brewster angle microscopy study

文献类型:期刊论文

作者Tian, CH; Wang, XL; Wu, T; Shen, JQ; Zhang, MH; Shen, T
刊名THIN SOLID FILMS
出版日期2001-06-01
卷号388期号:1-2页码:120-125
关键词Monolayer Hypocrellins Air/water Interface Brewster Angle Microscopy
ISSN号0040-6090
英文摘要The monolayer behavior at the air/water interface of the natural pigments hypocrellin A (HA), hypocrellin B (HB) and their butyl-amino derivatives (HAD, HBD) was investigated using Brewster angle microscopy (BAM). The results showed that stable monolayers were established with different phase transitions when the films were compressed. The collapse pressures of HA, HE, HAD and HBD were 30.3, 31.0, 34.8 and 35.5 mN m(-1), respectively which suggests that the butyl-amino substituents and the perylenoquinone rings of HAD and HBD are coplanar. The monolayer morphologies recorded by BAM showed differences among the images of these four compounds. Aggregation of HA, which may be attributed to the intermolecular hydrogen bonds between the two molecules, was observed. No obvious domains in the monolayers of HAD and HBD were observed using BAM, indicating that no large aggregations were formed in the monolayers. (C) 2001 Published by Elsevier Science B.V. All rights reserved.
语种英语
WOS记录号WOS:000168403900019
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/77519]  
专题中国科学院化学研究所
通讯作者Shen, T
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Tian, CH,Wang, XL,Wu, T,et al. Langmuir monolayer of hypocrellins and their amino substituted derivatives at the air/water interface: Brewster angle microscopy study[J]. THIN SOLID FILMS,2001,388(1-2):120-125.
APA Tian, CH,Wang, XL,Wu, T,Shen, JQ,Zhang, MH,&Shen, T.(2001).Langmuir monolayer of hypocrellins and their amino substituted derivatives at the air/water interface: Brewster angle microscopy study.THIN SOLID FILMS,388(1-2),120-125.
MLA Tian, CH,et al."Langmuir monolayer of hypocrellins and their amino substituted derivatives at the air/water interface: Brewster angle microscopy study".THIN SOLID FILMS 388.1-2(2001):120-125.

入库方式: OAI收割

来源:化学研究所

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