Synthesis and characterization of a soluble ladderlike polysilsesquioxane containing reactive ester groups
文献类型：期刊论文
| 作者 | Liu, Y; Liu, CQ; Shen, ZR; Xie, P; Zhang, RB; He, CB; Chung, TS |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2001-03-01 |
| 卷号 | 19期号:2页码:209-216 |
| 关键词 | Ladderlike Polysilsesquioxane Stepwise Coupling Polymerization Hydrosilylation Characterization |
| ISSN号 | 0256-7679 |
| 英文摘要 | A novel soluble ladderlike polysilsesquioxane containing reactive ester groups (Ester-T) was synthesized for the first time by stepwise coupling polymerization including preammonolysis, controlled hydrolysis and polycondensation. The monomer, 3-trichlorosilylpropoxy 4-acetoxybenzoate (M), was synthesized by hydrosilylation of allyloxy 4-acetoxybenzoate with trichlorosilane in the presence of dicyclopentadienylplatinum (II) chloride (Cp2PtCl2) catalyst. Combination of FTIR, H-1-NMR, C-13-NMR, Si-29-NMR, XRD, DSC, TGA and VPO methods was used to demonstrate that the polymer obtained has an ordered ladderlike structure. The synthesized Ester-T may have promising applications as a precursor of advanced functional polymers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000167446700012 |
| 出版者 | SPRINGER-VERLAG BERLIN |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77559]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | Chinese Acad Sci, PCLCC, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Y,Liu, CQ,Shen, ZR,et al. Synthesis and characterization of a soluble ladderlike polysilsesquioxane containing reactive ester groups[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2001,19(2):209-216. |
| APA | Liu, Y.,Liu, CQ.,Shen, ZR.,Xie, P.,Zhang, RB.,...&Chung, TS.(2001).Synthesis and characterization of a soluble ladderlike polysilsesquioxane containing reactive ester groups.CHINESE JOURNAL OF POLYMER SCIENCE,19(2),209-216. |
| MLA | Liu, Y,et al."Synthesis and characterization of a soluble ladderlike polysilsesquioxane containing reactive ester groups".CHINESE JOURNAL OF POLYMER SCIENCE 19.2(2001):209-216. |
入库方式： OAI收割
来源：化学研究所
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