Unusual rheological behaviors of linear PE and PE/kaolin composite
文献类型：期刊论文
| 作者 | Wu, QY; Wang, X; Gao, WP; Hu, YL; Qi, ZN |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2001-06-20 |
| 卷号 | 80期号:12页码:2154-2161 |
| 关键词 | Linear Pe Kaolin Composite Polymerization Filling Unusual Rheological Behavior |
| ISSN号 | 0021-8995 |
| 英文摘要 | The unusual flow behaviors of linear PE melts are caused by high molecular weight, tight entanglements of molecular chains, and strong adsorption of the melt at the capillary wall. Especially, the extreme change of interface adsorption is followed by an unusual flow, and at the molecular level, the dynamic variety of entanglement and disentanglement between the adsorption chain near the wall and the nonadsorption chain is the cause of the extrusion pressure vibration. Ultrahigh molecular weight polyethylene (UHMWPE)/kaolin composites prepared by polymerization filling could be smoothly extruded through the capillary. Also, with increase of the kaolin content, the apparent viscosity of the composite decreased and the processability was improved. Under slip boundary conditions, the real shear rate and shear stress of the melt near the capillary wall were reduced. The viscosity descent (desorption) and the deformation energy decrease of the melt near the wall were the important preconditions to gain a steady flow in a second glossy zone. (C) 2001 John Wiley & Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000167862400005 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77581]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, QY |
| 作者单位 | 1.Qingdao Inst Chem Technol, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, QY,Wang, X,Gao, WP,et al. Unusual rheological behaviors of linear PE and PE/kaolin composite[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2001,80(12):2154-2161. |
| APA | Wu, QY,Wang, X,Gao, WP,Hu, YL,&Qi, ZN.(2001).Unusual rheological behaviors of linear PE and PE/kaolin composite.JOURNAL OF APPLIED POLYMER SCIENCE,80(12),2154-2161. |
| MLA | Wu, QY,et al."Unusual rheological behaviors of linear PE and PE/kaolin composite".JOURNAL OF APPLIED POLYMER SCIENCE 80.12(2001):2154-2161. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。