Synthesis and characterization of polyorganosiloxane (POS) containing nano-scale tubular structure and its supramolecular clathrate
文献类型：期刊论文
| 作者 | Liu, CQ; Xie, P; Dai, DR; Zhang, RB; Zhu, CF; Wang, C |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2001-11-01 |
| 卷号 | 12期号:11-12页码:626-636 |
| 关键词 | Polyorganosiloxane Nano-scale Tubular Structure Hydrosilylation Supramolecular Clathrate |
| ISSN号 | 1042-7147 |
| 英文摘要 | A new polyorganosiloxane (POS) was synthesized successfully according to two plus two (2 + 2) mode by hydrosilylation reaction of reactive cis-isotactic ladder-like polyallylsilsesquioxane (Allyl-T) with coupling agent 1,1,3,3-tetratizetliyldisiloxane (H-MM) using di-cyclopentadienyl-dichloroplatinium (Cp2PtCl2) as catalyst. Moreover, a novel supramolecular POS clathrate (POS/C) was formed by in situ encapsulating rod-like liquid crystal molecule within the pore of POS. The Allyl-T was prepared by stepwise coupling polymerization. A variety of characterization methods including solubility test, FT-IR, H-1 - NMR, differential scanning calorimetry (DSC) gel permeation chromatography (GPC), vapor pressure osmometry (VPO), X-ray diffraction (XRD), atomic force microscopy (AFM), polarized optical microscopy (POM) and molecular simulation not only indicates nano-scale tubular structures exist in the POS though some defective structures still exist, but also proves that novel soluble supramolecular clathrate has been formed. Copyright (C) 2000 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173124400004 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77599]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, PCLCC Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Xie, P,Dai, DR,et al. Synthesis and characterization of polyorganosiloxane (POS) containing nano-scale tubular structure and its supramolecular clathrate[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2001,12(11-12):626-636. |
| APA | Liu, CQ,Xie, P,Dai, DR,Zhang, RB,Zhu, CF,&Wang, C.(2001).Synthesis and characterization of polyorganosiloxane (POS) containing nano-scale tubular structure and its supramolecular clathrate.POLYMERS FOR ADVANCED TECHNOLOGIES,12(11-12),626-636. |
| MLA | Liu, CQ,et al."Synthesis and characterization of polyorganosiloxane (POS) containing nano-scale tubular structure and its supramolecular clathrate".POLYMERS FOR ADVANCED TECHNOLOGIES 12.11-12(2001):626-636. |
入库方式： OAI收割
来源：化学研究所
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