Theoretical studies on the cyclic voltammograms of intercalation electrode reactions
文献类型:期刊论文
作者 | Wu, HQ; Li, YF |
刊名 | ACTA CHIMICA SINICA
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出版日期 | 2001 |
卷号 | 59期号:6页码:871-876 |
关键词 | Intercalation Electrode Reaction Cyclic Voltammograms Theoretical Studies |
ISSN号 | 0567-7351 |
英文摘要 | The cyclic voltammgrams of intercalation electrode reactions usually show a large potential difference between the oxidation peak and the reduction peak. A very low potential sweep rate is often required in the cyclic voltammetric measurement. On the basis of the thermodynamic equation and the charge transfer kinetic equation of the intercalation electrode reactions, its cyclic voltammograms are treated theoretically. In the treatment, the effects of such parameters as the thermodynamic parameter b, kinetic parameters D and k, potential sweep rate v, and the electrode resistance on the cyclic voltammograms are discussed. The features of the cyclic voltammograms are explained according to the theoretical calculation. |
语种 | 英语 |
WOS记录号 | WOS:000169511700012 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/77729] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wu, HQ |
作者单位 | 1.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, HQ,Li, YF. Theoretical studies on the cyclic voltammograms of intercalation electrode reactions[J]. ACTA CHIMICA SINICA,2001,59(6):871-876. |
APA | Wu, HQ,&Li, YF.(2001).Theoretical studies on the cyclic voltammograms of intercalation electrode reactions.ACTA CHIMICA SINICA,59(6),871-876. |
MLA | Wu, HQ,et al."Theoretical studies on the cyclic voltammograms of intercalation electrode reactions".ACTA CHIMICA SINICA 59.6(2001):871-876. |
入库方式: OAI收割
来源:化学研究所
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