Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters
文献类型：期刊论文
| 作者 | Yan, XP; Liu, MH; Liu, HF; Liew, KY; Zhao, N |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2001-05-14 |
| 卷号 | 170期号:1-2页码:203-208 |
| 关键词 | Metal Complex Colloidal Ruthenium Clusters Hydrogenation O-chloronitrobenzene |
| ISSN号 | 1381-1169 |
| 英文摘要 | Effect of metal complex on hydrogenation of o-chloronitrobenzene (o-CNB) over poly-vinylpyrrolidone stabilized ruthenium colloid (PVP-Ru) has been studied in methanol media under 320 K and 4.0 MPa. The addition of Zn(II) complexes of diamines to PVP-Ru catalyst system leads to significant increase in the activity of PVP-Ru, while the selectivity for o-chloroaniline (o-CAN) maintained similar to 100%. Especially, rate enhancement more than 30 times that over neat PVP-Ru has been achieved in the presence of Zn(trien)Cl-2. It was verified that the incorporation of Zn(II) complexes of multi-amines changed the reaction kinetics. (C) 2001 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000168613100022 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77751]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | 1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Univ Sains Malaysia, Sch Chem Sci, Pulau Pinang 11800, Malaysia |
| 推荐引用方式 GB/T 7714 | Yan, XP,Liu, MH,Liu, HF,et al. Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,170(1-2):203-208. |
| APA | Yan, XP,Liu, MH,Liu, HF,Liew, KY,&Zhao, N.(2001).Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,170(1-2),203-208. |
| MLA | Yan, XP,et al."Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 170.1-2(2001):203-208. |
入库方式： OAI收割
来源：化学研究所
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