IR spectra at various temperatures for potassium hydrogen difluoride
文献类型：期刊论文
| 作者 | Wu, KZ; Zuo, P; Zhang, JL; Liu, XD |
| 刊名 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2001-05-15 |
| 卷号 | 17期号:3页码:435-438 |
| 关键词 | Potassium Hydrogen Difluoride Solid-solid Phase Transition Ir Spectra At Various temperAtures |
| ISSN号 | 1001-4861 |
| 英文摘要 | The solid-solid phase transition of KHF2 was studied by infrared spectrometry at various temperatures and by differential scanning calorimetry(DSC) also. There are hydrogen bonds between the molecules which play a dominant role to the structure at low temperature state. In the temperature range closely corresponding to the solid-solid phase transition, the frequency of antisymmetric stretching(nu (3)) shifted to a higher wavenumber, and the bending(nu (2)) to lower wavenumber. The enthalpy and the temperature of solid-solid phase transition for KHF2 were measured by DSC method and the latter is consistent with the result of IR which could declare the mechanism of solid-solid phase transition of KHF2. With the breaking of hydrogen bonds between the molecules and the introduction of vibrational and rotational disorder KHF2 exhibited crystalline transition. |
| 语种 | 英语 |
| WOS记录号 | WOS:000168792300024 |
| 出版者 | CHINESE CHEMICAL SOCIETY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77785]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, KZ |
| 作者单位 | 1.Hebei Normal Univ, Dept Chem, Shijiazhuang 050016, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, KZ,Zuo, P,Zhang, JL,et al. IR spectra at various temperatures for potassium hydrogen difluoride[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2001,17(3):435-438. |
| APA | Wu, KZ,Zuo, P,Zhang, JL,&Liu, XD.(2001).IR spectra at various temperatures for potassium hydrogen difluoride.CHINESE JOURNAL OF INORGANIC CHEMISTRY,17(3),435-438. |
| MLA | Wu, KZ,et al."IR spectra at various temperatures for potassium hydrogen difluoride".CHINESE JOURNAL OF INORGANIC CHEMISTRY 17.3(2001):435-438. |
入库方式： OAI收割
来源：化学研究所
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