Preparation and characterization of microcellular polystyrene/LCP in situ composites by using supercritical CO2
文献类型:期刊论文
作者 | Wang, J; Cheng, XG; Yuan, MJ; He, JS |
刊名 | ACTA POLYMERICA SINICA
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出版日期 | 2001-08-01 |
期号 | 4页码:541-544 |
关键词 | Microcellular Polymer Supercritical Co2 Ps/lcp In Situ Composites Sulfonafted Ps |
ISSN号 | 1000-3304 |
英文摘要 | Microcellular polystyrene/LCP in situ composites with cell diameter less than 4 mum are prepared by using pressure quenching after supercritical CO2 saturating at 25 MPa, 80 degreesC for 6 h. Characterization of the microcellular structure of these blends is conducted to reveal the influence of LCP addition, LCP ratio and compatibilizer on the microcellular blends. The typical structure of these microcellular PS/LCP blends is that the microvoids only exist in the polystyrene phase. This structure results from the poor adsorption of supercritical CO2 by LCP under the experimental conditions. The cell diameter of the microcellular blends is smaller than that of microcellular PS. An increase of cell size is also found from skin to core in microcellular blends. The microcellular blends with ZnSPS has larger cell size than those without ZnSPS, which is the consequence of the improvement of interfacial adhesion. It is because CO2 could easily diffuse, out through the gap between poor adhesion interface of blends without ZnSps. |
语种 | 英语 |
WOS记录号 | WOS:000170584200026 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/77787] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, J |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, J,Cheng, XG,Yuan, MJ,et al. Preparation and characterization of microcellular polystyrene/LCP in situ composites by using supercritical CO2[J]. ACTA POLYMERICA SINICA,2001(4):541-544. |
APA | Wang, J,Cheng, XG,Yuan, MJ,&He, JS.(2001).Preparation and characterization of microcellular polystyrene/LCP in situ composites by using supercritical CO2.ACTA POLYMERICA SINICA(4),541-544. |
MLA | Wang, J,et al."Preparation and characterization of microcellular polystyrene/LCP in situ composites by using supercritical CO2".ACTA POLYMERICA SINICA .4(2001):541-544. |
入库方式: OAI收割
来源:化学研究所
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