Interaction of water-soluble tetrakis-(1-methyl-4-pyridiniyl)porphyrin and CdS naonoparticles
文献类型：期刊论文
| 作者 | Tian, CH; He, XZ; Zhou, YL; Shen, T |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2001-11-01 |
| 卷号 | 19期号:11页码:1028-1032 |
| 关键词 | Water-soluble Porphyrin Colloidal Cds Nanoparticles Fluorescence Quenching |
| ISSN号 | 1001-604X |
| 英文摘要 | The interaction between positively charged porphyrin TMPyP(4) (tetrakis-(1-methyl-4-pyridiniyl)porphyrin) and negatively charged surface of colloidal CdS nanoparticles has been studied by absorption spectrum, fluorescence spectroscopy, and time-correlated single-photon-counting methods. Addition of CdS colloid to a TMPyP(4) solution leads to TMPyP(4) adsorption onto the surface of US colloid with an apparent association constant of 4643 L/mol. This adsorption results in distinct changes in absorption spectrum of TMPyP (4) and the quenching of its' fluorescence, but the biexponential fluorescence decay changes hardly. Nearly 90% of the fluorescence of 5 x 10(-6) mol/L TMPyP(4) can be quenched with 1.5 x 10(-4) mol/L CdS colloid. These spectral changes are attributed to the formation of a certain form complex TMPyP(4)-CdS. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173220900003 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77811]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tian, CH |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, CH,He, XZ,Zhou, YL,et al. Interaction of water-soluble tetrakis-(1-methyl-4-pyridiniyl)porphyrin and CdS naonoparticles[J]. CHINESE JOURNAL OF CHEMISTRY,2001,19(11):1028-1032. |
| APA | Tian, CH,He, XZ,Zhou, YL,&Shen, T.(2001).Interaction of water-soluble tetrakis-(1-methyl-4-pyridiniyl)porphyrin and CdS naonoparticles.CHINESE JOURNAL OF CHEMISTRY,19(11),1028-1032. |
| MLA | Tian, CH,et al."Interaction of water-soluble tetrakis-(1-methyl-4-pyridiniyl)porphyrin and CdS naonoparticles".CHINESE JOURNAL OF CHEMISTRY 19.11(2001):1028-1032. |
入库方式： OAI收割
来源：化学研究所
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