Synthesis and characterization of the conjugated poly(phenylene) with chiral binaphthyl crown ether as pendent group
文献类型：期刊论文
| 作者 | Liu, HW; Tang, WH; Jiang, J; Zhao, YL; Chen, CF; Xi, F |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2001 |
| 卷号 | 59期号:10页码:1841-1845 |
| 关键词 | Optically Active Conjugated Polymer Crown Ether Chiral Binaphthol Poly(Phenylene) |
| ISSN号 | 0567-7351 |
| 英文摘要 | A novel optically active poly(phenylene) substituted with chiral binaphthyl crown ether functional group has been synthesized by using the palladium - catalyzed Suzuki cross - coupling reaction. The structure and properties of the polymer were characterized with H-1 NMR, UV, CD, fluorescence spectroscopic, thermal gravimetric analyses and differential scanning calorimetry. It is found that the polymer exihibits high thermal stability and high specific optical rotation. In addition, the polymer can bind alkali - metal ions in solution and the fluorescence of the polymer is gradually attenuated with the increasing of concentration of alkali - metal ions. This polymer emits strong blue light when irradiated and is expected to have the potential application for blue light emitting materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000171884400057 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77913]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, F |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HW,Tang, WH,Jiang, J,et al. Synthesis and characterization of the conjugated poly(phenylene) with chiral binaphthyl crown ether as pendent group[J]. ACTA CHIMICA SINICA,2001,59(10):1841-1845. |
| APA | Liu, HW,Tang, WH,Jiang, J,Zhao, YL,Chen, CF,&Xi, F.(2001).Synthesis and characterization of the conjugated poly(phenylene) with chiral binaphthyl crown ether as pendent group.ACTA CHIMICA SINICA,59(10),1841-1845. |
| MLA | Liu, HW,et al."Synthesis and characterization of the conjugated poly(phenylene) with chiral binaphthyl crown ether as pendent group".ACTA CHIMICA SINICA 59.10(2001):1841-1845. |
入库方式： OAI收割
来源：化学研究所
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