Synthesis and characterization of a novel soluble reactive ladder-like polysilsesquioxane with side-chain 2-(4-chloromethyl phenyl) ethyl groups
文献类型：期刊论文
| 作者 | Liu, CQ; Liu, Y; Xie, P; Dai, DR; Zhang, RB |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2001-08-01 |
| 卷号 | 12期号:8页码:475-481 |
| 关键词 | Ladder-like Polysilsesquioxane Stepwise Coupling Polymerization Hydrosilylation 2-(4-chloro-mEthyl Phenyl) Ethyl Groups Characterization |
| ISSN号 | 1042-7147 |
| 英文摘要 | A new kind of soluble structure-ordered ladder-like polysilsesquioxane with reactive side-chain 2-(4-chloromethyl phenyl) ethyl groups (L) was first synthesized by stepwise coupling polymerization. The monomer, 2-(4-chloromethyl phenyl) ethyltrichlorosilane (M), was synthesized successfully by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (CP2PtCl2) catalyst. Monomer and polymer structures were characterized by FT-IR, H-1-NMR, C-13-NMR, Si-29-NMR, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), vapor pressure osmometry (VPO) and X-ray diffraction (XRD) This novel reactive ladder-like polymer has promise potential applications as initiator for atom transfer radical polymerization, and as precursor for a variety of advanced functional polymers. Copyright (C) 2001 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000170793200004 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77957]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, China Petrochem Corp, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Liu, Y,Xie, P,et al. Synthesis and characterization of a novel soluble reactive ladder-like polysilsesquioxane with side-chain 2-(4-chloromethyl phenyl) ethyl groups[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2001,12(8):475-481. |
| APA | Liu, CQ,Liu, Y,Xie, P,Dai, DR,&Zhang, RB.(2001).Synthesis and characterization of a novel soluble reactive ladder-like polysilsesquioxane with side-chain 2-(4-chloromethyl phenyl) ethyl groups.POLYMERS FOR ADVANCED TECHNOLOGIES,12(8),475-481. |
| MLA | Liu, CQ,et al."Synthesis and characterization of a novel soluble reactive ladder-like polysilsesquioxane with side-chain 2-(4-chloromethyl phenyl) ethyl groups".POLYMERS FOR ADVANCED TECHNOLOGIES 12.8(2001):475-481. |
入库方式： OAI收割
来源：化学研究所
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