Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts
文献类型：期刊论文
| 作者 | Yan, XP; Liu, MH; Liu, HF; Liew, KY |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2001-03-28 |
| 卷号 | 169期号:1-2页码:225-233 |
| 关键词 | Hydrogenation Ruthenium Colloid O-chloronitrobenzene Boron Species |
| ISSN号 | 1381-1169 |
| 英文摘要 | The role of boron species in selective hydrogenation of o-chloronitrobenzene (o-CNB) over polymer-stabilized ruthenium colloids has been studied. Of the two kinds of boron species (boride and berate) present in ruthenium colloids prepared by NaSH4 reduction, it was verified that only berate had a significant effect on the hydrogenation of o-CNB, while boride performed as a spectator. When metal cations were added into ruthenium colloidal catalyst system as modifiers, respectively, we observed that the synergetic effect between berate and metal cations occurred in these systems. It is suggested that metal complex ions were formed between the metal cations and berate ions. (C) 2001 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000167803100027 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77967]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | 1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Polymer Chem Lab,PCLCC, Beijing 100080, Peoples R China 2.China Petro Chem Corp, Beijing 100080, Peoples R China 3.Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia |
| 推荐引用方式 GB/T 7714 | Yan, XP,Liu, MH,Liu, HF,et al. Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,169(1-2):225-233. |
| APA | Yan, XP,Liu, MH,Liu, HF,&Liew, KY.(2001).Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,169(1-2),225-233. |
| MLA | Yan, XP,et al."Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 169.1-2(2001):225-233. |
入库方式： OAI收割
来源：化学研究所
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