Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state
文献类型:期刊论文
作者 | Zeng, QD; Wang, C; Xu, SD; Bai, CL; Li, Y; Yan, XJ |
刊名 | APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
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出版日期 | 2001-08-01 |
卷号 | 73期号:2页码:247-250 |
ISSN号 | 0947-8396 |
英文摘要 | Nanostructures are formed by photodimerization of crystalline 4,4'-dimethylbenzophenone (1) through intermolecular hydrogen abstraction and Baeyer-Villiger reaction of 1 with m-chloroperoxybenzoic acid (MCPBA) (5) in the solid state. Atomic force microscopy (AFM) reveals that the crystal face 001) of 1 during photodimerization exhibits volcanoes, whereas the same face (001) of 1 yields both craters and volcanoes all over the surface from the contact edge of the crystals during the Baeyer-Villiger reaction. All the experimental results are correlated with the bulk crystal structure. Molecular interpretation of the AFM features of 1 is given. |
语种 | 英语 |
WOS记录号 | WOS:000170335700020 |
出版者 | SPRINGER-VERLAG |
源URL | [http://ir.iccas.ac.cn/handle/121111/78039] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Bai, CL |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng, QD,Wang, C,Xu, SD,et al. Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,2001,73(2):247-250. |
APA | Zeng, QD,Wang, C,Xu, SD,Bai, CL,Li, Y,&Yan, XJ.(2001).Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state.APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,73(2),247-250. |
MLA | Zeng, QD,et al."Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state".APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING 73.2(2001):247-250. |
入库方式: OAI收割
来源:化学研究所
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