Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone
文献类型：期刊论文
| 作者 | Huang, K; Xue, L; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2001-11-01 |
| 卷号 | 12期号:11-12页码:647-650 |
| 关键词 | Methylcellulose-l-proline-pt Complex Asymmetric Hydrogenation Optical Selectivity Propiophenone |
| ISSN号 | 1042-7147 |
| 英文摘要 | A new chiral polymer-metal complex, silica-supported methylcellulose-L-proline-Pt complex (SiO2-MC-LP-Pt) has been found to be a high optically active catalyst for asymmetric hydrogenation of propiophenone to (R)-1-phenyl-1-propanol at 30degreesC and under atmospheric hydrogen pressure. The product and optical yields of 1-phenyl-1-propanol amounted to 62.5 and 92.2%, respectively. The product and optical yields were remarkably affected by the Pt content in the complex, the kind of solvent and the reaction temperature. This catalyst was very stable and could be reused several times without remarkable change in optical catalytic activity. Copyright (C) 2001 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173124400007 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78079]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, K |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, K,Xue, L,Huang, MY,et al. Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2001,12(11-12):647-650. |
| APA | Huang, K,Xue, L,Huang, MY,&Jiang, YY.(2001).Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone.POLYMERS FOR ADVANCED TECHNOLOGIES,12(11-12),647-650. |
| MLA | Huang, K,et al."Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone".POLYMERS FOR ADVANCED TECHNOLOGIES 12.11-12(2001):647-650. |
入库方式： OAI收割
来源：化学研究所
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