Structures, energy bands and conductivities of (Me3NEt)[Pd(dmit)(2)](2) and (NEt4)[Pd(dmit)(2)](2)
文献类型：期刊论文
| 作者 | Fang, Q; Lei, H; Liu, Z; Zhang, B; Sun, YM; Mak, TCW |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2002-02-01 |
| 卷号 | 45期号:1页码:97-105 |
| 关键词 | Conductive Complex Crystal Structure Energy Band Conductivity |
| ISSN号 | 1006-9291 |
| 英文摘要 | The electrical conductive molecular crystals (Me3NEt)[Pd(dmit)(2)](2). and (NEt4)[Pd (dmit)(2)](2) (dmit = 4,5-dimercapto-1,3-dithiole-2-thione) have been prepared, and their crystal structures and conductivity-temperature curves have been determined. The fact that the conductivity at room temperature of (Me3NEt)[Pd(dmit)(2)](2) (sigma = 58 Omega(-1) . cm(-1)) is much higher than that of (NEt4)[Pd(dmit)(2)](2) (sigma = 2.2 Omega(-1) . cm(-1)) has been rationally explained by the results of energy band calculations. (MeNEt3)[Pd(dmit)(2)](2) belongs to monoclinic system, P2(1)/m space group and (NEt4)[Pd(dmit)(2)](2) belongs to triclinic system, P (1) over bar space group. The structural conducting component of the crystals is the planar coordinative anion [Pd(dmit)(2)](0.5-) which forms the face-to-face dimmer [Pd(dmit)(2)](2)(-). These dimers have been further constructed to be a kind of two-dimensional (2-D) conductive molecular sheet by means of S...S intermolecular interactions. The tiny difference of the above 2-D molecular sheets of the two title crystals has resulted in one order of magnitude difference of conductivities. |
| 语种 | 英语 |
| WOS记录号 | WOS:000175271500014 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78097]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fang, Q |
| 作者单位 | 1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Shandong Univ, Sch Informat Sci & Engn, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 4.Southeast Univ, Dept Chem & Chem Engn, Nanjing 210096, Peoples R China 5.Chinese Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Q,Lei, H,Liu, Z,et al. Structures, energy bands and conductivities of (Me3NEt)[Pd(dmit)(2)](2) and (NEt4)[Pd(dmit)(2)](2)[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2002,45(1):97-105. |
| APA | Fang, Q,Lei, H,Liu, Z,Zhang, B,Sun, YM,&Mak, TCW.(2002).Structures, energy bands and conductivities of (Me3NEt)[Pd(dmit)(2)](2) and (NEt4)[Pd(dmit)(2)](2).SCIENCE IN CHINA SERIES B-CHEMISTRY,45(1),97-105. |
| MLA | Fang, Q,et al."Structures, energy bands and conductivities of (Me3NEt)[Pd(dmit)(2)](2) and (NEt4)[Pd(dmit)(2)](2)".SCIENCE IN CHINA SERIES B-CHEMISTRY 45.1(2002):97-105. |
入库方式： OAI收割
来源：化学研究所
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