Influence of water on adsorption properties of lithium exchanged low silica X zeolite
文献类型:期刊论文
作者 | Jiang, H; Zhao, BY; Xie, YC |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2002-07-01 |
卷号 | 18期号:7页码:577-580 |
关键词 | Water Adsorption Air Separation Low Silica x Zeolite |
ISSN号 | 1000-6818 |
DOI | 10.3866/PKU.WHXB20020701 |
英文摘要 | This paper shows quantitatively the consequence of adsorbed water on N-2 or O-2 adsorbed on LiLSX lithium exchanged low silica X zeolite. In the range of 0 similar to 32 H2O/u.c. (unit cell), water present in LiLSX sharply declined the capacity for N-2 or O-2 adsorption. The reason is that the adsorption mainly occurs on the Li+ ions on the 32 SIII sites in LiLSX. When H2O molecules residual after the desorption of hydrated LiLSX are adsorbed tightly on Li+ at SIR site, they block the adsorption of nitrogen or oxygen. Water molecules introduced from outside into the dehydrated LiLSX influence the adsorption of nitrogen less seriously than the residual water molecules do, because of the heterogeneity of adsorption sites and the diffusion behavior of water in LiLSX. When diffused into the inner part of a LiLSX particle, some water molecules may adsorb on weaker sites other than the strongest SIII sites. |
语种 | 英语 |
WOS记录号 | WOS:000177048000001 |
出版者 | PEKING UNIV PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/78163] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xie, YC |
作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, H,Zhao, BY,Xie, YC. Influence of water on adsorption properties of lithium exchanged low silica X zeolite[J]. ACTA PHYSICO-CHIMICA SINICA,2002,18(7):577-580. |
APA | Jiang, H,Zhao, BY,&Xie, YC.(2002).Influence of water on adsorption properties of lithium exchanged low silica X zeolite.ACTA PHYSICO-CHIMICA SINICA,18(7),577-580. |
MLA | Jiang, H,et al."Influence of water on adsorption properties of lithium exchanged low silica X zeolite".ACTA PHYSICO-CHIMICA SINICA 18.7(2002):577-580. |
入库方式: OAI收割
来源:化学研究所
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