Small angle light scattering measurement of the isotropic to nematic transition of a side chain nematic polymethacrylate
文献类型：期刊论文
| 作者 | Hu, ZM; Qian, RY; Chen, SX; Chen, XF; Zhou, QF |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2002-09-01 |
| 卷号 | 20期号:5页码:431-437 |
| 关键词 | Side Chain Nematic Polymer Isotropic-nematic Transition Small Angle Depolarized Light Scattering |
| ISSN号 | 0256-7679 |
| 英文摘要 | The kinetics of I-->N transition of a side chain nematic polymethacrylate has been studied by small angle depolarized light scattering intensity measurements using a charge coupled device linear image sensor. The polymer shows the transition temperatures K52N79I in degreesC, The H-v scattering intensity T(q,t) during the transition I (at 80.2degreesC)-->N (at 75.8degreesC) shows that T(q) is independent of q for all t, and during the initial stage (in 6 s) T(t) increases exponentially with t. In the later stage of the transition T(t) approaches a saturation value in 2 min. This experimental result indicates that the I-->N transition of a liquid crystalline polymer is a spinodal type of phase transition mediated by orientation fluctuation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000177869300007 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78207]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Qian, RY |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Dept Polymer Sci & Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, ZM,Qian, RY,Chen, SX,et al. Small angle light scattering measurement of the isotropic to nematic transition of a side chain nematic polymethacrylate[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2002,20(5):431-437. |
| APA | Hu, ZM,Qian, RY,Chen, SX,Chen, XF,&Zhou, QF.(2002).Small angle light scattering measurement of the isotropic to nematic transition of a side chain nematic polymethacrylate.CHINESE JOURNAL OF POLYMER SCIENCE,20(5),431-437. |
| MLA | Hu, ZM,et al."Small angle light scattering measurement of the isotropic to nematic transition of a side chain nematic polymethacrylate".CHINESE JOURNAL OF POLYMER SCIENCE 20.5(2002):431-437. |
入库方式： OAI收割
来源：化学研究所
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