Non-isothermal crystallization behavior and kinetics of metallocene short chain branched polyethylene
文献类型：期刊论文
| 作者 | Peng, Y; Fu, Q; Liu, JP; He, TB |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2002-06-01 |
| 卷号 | 23期号:6页码:1183-1188 |
| 关键词 | Metallocene Short Branched Polyethylene Non-isothermal Crystallization Molecular Weight Branching Content |
| ISSN号 | 0251-0790 |
| 英文摘要 | The non-isothermal crystallization behavior and kinetics of metallocene short chain branched polyethylene were investigated via DSC at cooling rates from 2.5 to 20 degreesC/min, and subsequent heating at rate of 10 degreesC/min. To verify the effect of molecular weight and branching content on crystallization, three group samples were chosen: (1) linear polyethylene with low molecular weight and high molecular weight; (2) low molecular weight polyethylene with low branching content and high branching content; (3) high molecular weight polyethylene with low branching content and high branching content. The results show that crystallization temperature, crystallinity, melting temperature and crystallization rate are highly branching content-dependent. Molecular weight effect is less important, compared to branching content. A dramatic decrease of crystallization temperature, crystallinity, crystallization rate and melting temperature was observed for branched samples. The non-isothermal kinetics was analyzed via the methods, developed by Gupta and Mo Zhi-shen, and good agreement was obtained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000176272300053 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78241]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fu, Q |
| 作者单位 | 1.Sichuan Univ, State Key Lab Polymer Mat Engn, Dept Polymer Sci & Mat, Chengdu 610065, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Y,Fu, Q,Liu, JP,et al. Non-isothermal crystallization behavior and kinetics of metallocene short chain branched polyethylene[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(6):1183-1188. |
| APA | Peng, Y,Fu, Q,Liu, JP,&He, TB.(2002).Non-isothermal crystallization behavior and kinetics of metallocene short chain branched polyethylene.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(6),1183-1188. |
| MLA | Peng, Y,et al."Non-isothermal crystallization behavior and kinetics of metallocene short chain branched polyethylene".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.6(2002):1183-1188. |
入库方式： OAI收割
来源：化学研究所
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