中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Artificial ESR study on participation of histidine in the secondary electron transfer inside photosystem II reaction center

文献类型:期刊论文

作者Liu, HF; Liu, Y; Wang, P; Zhang, QY
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
出版日期2002-04-01
卷号23期号:4页码:724-726
关键词Imidazole Radical Secondary Electron Transfer Artificial SimulatiOn On Psi reactiOn Center Esr Spin Trapping
ISSN号0251-0790
英文摘要Upon the addition of imidazole (Im) to the artificial photosynthetic systems composed by ZnTPP/BQ and p-H2TPP-NH-CO-CH2-BQ, half-lives of ESR signals of semibenzoquinone radical BQ(.-) and -CH2-BQ(.-) are significantly prolonged by the secondary electron transfer pathway from imidazole to porphyrin cation in polar solvents. The imidazole cation radicals (Im can simultaneously be identified by PBN(spin trap) both in BQ/ZnTPP/Im and p-H2TPP-NH-CO-CH2-BQ systems when laser-flashing. On the basis of our ESR observation, a secondary electron transfer mechanism can be proposed as follows: (1) TPP+hv-->TPP*; (2) TPP*+BQ-->TPP.++BQ(.-); (3) TPP.++Im-->TPP+Im(.+).
语种英语
WOS记录号WOS:000175203800051
出版者HIGHER EDUCATION PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/78291]  
专题中国科学院化学研究所
通讯作者Liu, Y
作者单位Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, HF,Liu, Y,Wang, P,et al. Artificial ESR study on participation of histidine in the secondary electron transfer inside photosystem II reaction center[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(4):724-726.
APA Liu, HF,Liu, Y,Wang, P,&Zhang, QY.(2002).Artificial ESR study on participation of histidine in the secondary electron transfer inside photosystem II reaction center.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(4),724-726.
MLA Liu, HF,et al."Artificial ESR study on participation of histidine in the secondary electron transfer inside photosystem II reaction center".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.4(2002):724-726.

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来源:化学研究所

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