Studies on the synthesis and conductivity of a novel reactive ladder-like poly(beta-cyanoethylsilsesquioxane) and poly [(beta-cyanoethylsilsesquioxane)-co-(beta-methylsilsesquioxane)]
文献类型：期刊论文
| 作者 | Zhang, Y; Guo, GQ; Sun, J; Zhou, XS; Xie, P; Zhang, PB; Fu, PF |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2002-12-12 |
| 卷号 | 203期号:16页码:2351-2356 |
| 关键词 | Conductivity Stepwise Coupling Polymerization Ladder-like Polymers Poly(Silsesquioxane)s |
| ISSN号 | 1022-1352 |
| 英文摘要 | Two novel reactive poly(beta-cyanoethylsilses-quioxane) (CN-T) and poly[(beta-cyanoethylsilsesquioxane)-co-(beta-methylsilsesquioxane)] (CN-Me-T) have been synthesized successfully for the first time via stepwise cou;ling polymerization (SCP). A variety of characterization methods including FTIR, H-1 NMR Si-29 NMR, X-ray diffraction (XRD), differential scanning calorimetry (DSC) and vapor pressure osmometry (VPO) were combined to demonstrate that the structures of the title polymers possess ordered ladder-like structures. As expected, the ionic conductivity of these polymers mixed homogeneously with lithium perchlorate reached 10(-6) S.cm(-1) at room temperature and obviously increased with the raise of temperature. |
| 语种 | 英语 |
| WOS记录号 | WOS:000180766600012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78361]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, PB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci,State Key Lab Polymer Phys & Chem, PCLCC, Beijing 100080, Peoples R China 2.Dow Corning Corp, New Ventures R&D, Midland, MI 48686 USA |
| 推荐引用方式 GB/T 7714 | Zhang, Y,Guo, GQ,Sun, J,et al. Studies on the synthesis and conductivity of a novel reactive ladder-like poly(beta-cyanoethylsilsesquioxane) and poly [(beta-cyanoethylsilsesquioxane)-co-(beta-methylsilsesquioxane)][J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2002,203(16):2351-2356. |
| APA | Zhang, Y.,Guo, GQ.,Sun, J.,Zhou, XS.,Xie, P.,...&Fu, PF.(2002).Studies on the synthesis and conductivity of a novel reactive ladder-like poly(beta-cyanoethylsilsesquioxane) and poly [(beta-cyanoethylsilsesquioxane)-co-(beta-methylsilsesquioxane)].MACROMOLECULAR CHEMISTRY AND PHYSICS,203(16),2351-2356. |
| MLA | Zhang, Y,et al."Studies on the synthesis and conductivity of a novel reactive ladder-like poly(beta-cyanoethylsilsesquioxane) and poly [(beta-cyanoethylsilsesquioxane)-co-(beta-methylsilsesquioxane)]".MACROMOLECULAR CHEMISTRY AND PHYSICS 203.16(2002):2351-2356. |
入库方式： OAI收割
来源：化学研究所
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