Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol
文献类型：期刊论文
| 作者 | Huang, K; Xue, L; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2002-03-01 |
| 卷号 | 13期号:3-4页码:165-168 |
| 关键词 | Asymmetric Hydrogenation Diacetone Alcohol Silica-supported Methylcellulose-l-phenyl Alanine Platinum Complex |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.168 |
| 英文摘要 | A new chiral natural bio-polymer-metal complexe, silica-supported methylcellulose-L-phenyl alanine-platinum complex (SiO2-MC-L-Phe-Pt) has been prepared by a very simple method, and the Pt complex has been found to be able to catalyze the asymmetric hydrogenation of diacetone alcohol to give (R)-(-)-2-methyl-2,4-pentan-diol at room temperature and under atmospheric hydrogen pressure, The product and optical yields of 2-methyl-2,4-pentandiol amounted to 67.0 and 92.7%, respectively. The product and optical yields were remarkably affected by the Pt content in the complex, the kind of solvent and the reaction temperature. This catalyst was very stable and could be reused several times without any remarkable change in optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174200300002 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78503]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, K |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, K,Xue, L,Huang, MY,et al. Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):165-168. |
| APA | Huang, K,Xue, L,Huang, MY,&Jiang, YY.(2002).Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),165-168. |
| MLA | Huang, K,et al."Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):165-168. |
入库方式： OAI收割
来源：化学研究所
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