Theoretical study on the kinetics of electron transfer for bond-breaking reaction
文献类型：期刊论文
| 作者 | Xing, YM; Zhou, ZY; Gao, HW |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2002-06-01 |
| 卷号 | 20期号:6页码:539-544 |
| 关键词 | Electron Transfer Bond-breaking Reaction Butyl Halide |
| ISSN号 | 1001-604X |
| 英文摘要 | To test the theory of dissociative electron transfer, a simple model describing the kinetics of electron transfer bond-breaking reactions was used. The Hamiltonian of the system was given. The homogeneous and heterogeneous kinetic data fit reasonably well with an activation-driving force relationship derived from the Marcus quadratic theory. In the heterogeneous case, there is a good agreement between the theoretical calculation and the experimental result, while in the homogeneous case, a good agreement is only observed for the tertiary halides. This is due to the stability of tertiary radical resulting from the sterical effect. |
| 语种 | 英语 |
| WOS记录号 | WOS:000176074100003 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78511]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, ZY |
| 作者单位 | 1.Qufu Normal Univ, Dept Chem, Qufu 273165, Shandong, Peoples R China 2.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China 3.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China 4.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing, YM,Zhou, ZY,Gao, HW. Theoretical study on the kinetics of electron transfer for bond-breaking reaction[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(6):539-544. |
| APA | Xing, YM,Zhou, ZY,&Gao, HW.(2002).Theoretical study on the kinetics of electron transfer for bond-breaking reaction.CHINESE JOURNAL OF CHEMISTRY,20(6),539-544. |
| MLA | Xing, YM,et al."Theoretical study on the kinetics of electron transfer for bond-breaking reaction".CHINESE JOURNAL OF CHEMISTRY 20.6(2002):539-544. |
入库方式： OAI收割
来源：化学研究所
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