Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)
文献类型：期刊论文
| 作者 | Cui, DM; Tang, T; Cheng, JH; Hu, NH; Chen, WQ; Huang, BT |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2002-02-01 |
| 卷号 | 23期号:2页码:188-190 |
| 关键词 | Cyclopentylindene Samarium Rare Earth Complex |
| ISSN号 | 0251-0790 |
| 英文摘要 | Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 with two equivalents of C5H9C9H6Li. From mix-solvent of THF and hexane, red color single crystals were obtained. The crystal belongs to a cubic system, space group P2(1)3 with unit cell parameters a= b=c= 1. 754 0(2) nm, alpha=beta=gamma=90degrees, V=5. 396 4(11) nm(3), Z = 4. The ten-coordinated samarium atom is bonded to three cyclopentylindenyl rings and a chlorine atom to form the anionic part of the title complex, ring centroids and the chlorine atom form a tortured tetrahedron around samarium. In the cationic part, lithium atom coordinates to four oxygen atoms of THF molecules to form a normal tetrahedron. The Sm-C(within the same ring) distance varies from 0. 268 to 0. 299 nm. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174163300006 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78545]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Jilin Univ Technol, Dept Chem Engn, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, DM,Tang, T,Cheng, JH,et al. Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(2):188-190. |
| APA | Cui, DM,Tang, T,Cheng, JH,Hu, NH,Chen, WQ,&Huang, BT.(2002).Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4).CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(2),188-190. |
| MLA | Cui, DM,et al."Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.2(2002):188-190. |
入库方式： OAI收割
来源：化学研究所
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