Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone
文献类型：期刊论文
| 作者 | Huang, K; Xue, L; Hu, YC; Huang, MY; Jiang, YY |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2002 |
| 卷号 | 50期号:3页码:199-203 |
| 关键词 | (r)-(-)-4-methyl-2-pentanol Asymmetric Hydrogenation Silica-supported Starch Polysulfosiloxane-platinum Complex |
| ISSN号 | 1381-5148 |
| 英文摘要 | A new chiral natural bio-polymer-metal complexes. silica-supported starch-polysulfosiloxane-platinum complex (SiO2-ST-Si-S-Pt) has been prepared by a very simple method, and Pt complex has been found to be able to catalyze the asymmetric hydrogenation of 4-methyl-2-pentanone to give (R)-(-)-4-methyl-2-pentanol at room temperature and under an atmospheric hydrogen pressure. The product and optical yields of 4-methyl-2-pentanol a-mounted to 73.2 and 94.1%. respectively. (C) 2002 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174397400001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78579]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, K |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, K,Xue, L,Hu, YC,et al. Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone[J]. REACTIVE & FUNCTIONAL POLYMERS,2002,50(3):199-203. |
| APA | Huang, K,Xue, L,Hu, YC,Huang, MY,&Jiang, YY.(2002).Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone.REACTIVE & FUNCTIONAL POLYMERS,50(3),199-203. |
| MLA | Huang, K,et al."Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone".REACTIVE & FUNCTIONAL POLYMERS 50.3(2002):199-203. |
入库方式： OAI收割
来源：化学研究所
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