Investigation on photoexcited dynamics of IR-140 dye in ethanol by femtosecond supercontinuum-probing technique
文献类型:期刊论文
作者 | Wang, DL; Jiang, HB; Yang, H; Liu, CL; Gong, QH; Xiang, JF; Xu, GZ |
刊名 | JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS
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出版日期 | 2002-03-01 |
卷号 | 4期号:2页码:155-159 |
关键词 | Ultrafast Process Laser Materials Time-resolved Optical Spectroscopies |
ISSN号 | 1464-4258 |
英文摘要 | Transient absorption and emission spectra of IR-140 dye (5,5'-dichloro-11-diphenylamine-3,3'-diethyl- 10,12-ethylene-thiatricarbocyanine-perchlorate) in ethanol have been investigated by using the pump supercontinuum-probing technique of 130 fs time resolution. Excited at a wavelength of 807 nm, two peaks at 820 and 840 nm in the emission spectra were observed. The decay of stimulated emission (SE) at 840 nm can be fitted by a dual-exponential function. Meanwhile, a new transient absorption band ranging from 500 to 650 nm was observed and attributed to the transition between the excited singlet states. Its relaxation process could also be fitted by a dual -exponential function. Both relaxation processes of SE and excited-state absorption were probing wavelength-dependent and included a fast relaxation with a decay time of about several picoseconds and a slow relaxation with decay time longer than 0.1 ns. The prime energy structure was proposed according to the relaxation process and transient spectra of IR-140. |
语种 | 英语 |
WOS记录号 | WOS:000174908300007 |
出版者 | IOP PUBLISHING LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/78611] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Gong, QH |
作者单位 | 1.Beijing Univ, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China 2.Beijing Univ, Dept Phys, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China 4.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Stable & Unstable Speci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, DL,Jiang, HB,Yang, H,et al. Investigation on photoexcited dynamics of IR-140 dye in ethanol by femtosecond supercontinuum-probing technique[J]. JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS,2002,4(2):155-159. |
APA | Wang, DL.,Jiang, HB.,Yang, H.,Liu, CL.,Gong, QH.,...&Xu, GZ.(2002).Investigation on photoexcited dynamics of IR-140 dye in ethanol by femtosecond supercontinuum-probing technique.JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS,4(2),155-159. |
MLA | Wang, DL,et al."Investigation on photoexcited dynamics of IR-140 dye in ethanol by femtosecond supercontinuum-probing technique".JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS 4.2(2002):155-159. |
入库方式: OAI收割
来源:化学研究所
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