Preparation of PE/MMT nanocomposite by monomer intercalation and in situ copolymerization
文献类型：期刊论文
| 作者 | Guo, CY; Ma, Z; Zhang, MG; He, AH; Ke, YC; Hu, YL |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2002-08-01 |
| 卷号 | 47期号:15页码:1267-1270 |
| 关键词 | Pe/mmt Nanocomposites In Situ Intercalation Copolymerization |
| ISSN号 | 1001-6538 |
| 英文摘要 | The catalyst {[(2-ArN = C(Me))(2)C5H3N]FeCl2} (Ar = 2-C6H4(i-Pr)) with methylaluminoxane (MAO) as cocatalyst was intercalated between layers of montmorillonite (MMT) for ethylene oligomerization. Metallocene catalyst Me2Si(Ind)(2)ZrCl2 and MAO was then added to form a dual functional catalytic system. A PE/MMT nanocomposite was prepared by copolymerization of ethylene with alpha-olefins produced in situ from ethylene over the dual functional catalytic system. The catalytic system was of high polymeric activity. The resultant PE/MMT nanocomposites were stable and got increases in tensile strength and temperature of maximum weight loss (T-onset). |
| 语种 | 英语 |
| WOS记录号 | WOS:000177045600006 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78683]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, YL |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.China Natl Petr Corp Key Lab Catalysi, Beijing Lab Catalysis, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, CY,Ma, Z,Zhang, MG,et al. Preparation of PE/MMT nanocomposite by monomer intercalation and in situ copolymerization[J]. CHINESE SCIENCE BULLETIN,2002,47(15):1267-1270. |
| APA | Guo, CY,Ma, Z,Zhang, MG,He, AH,Ke, YC,&Hu, YL.(2002).Preparation of PE/MMT nanocomposite by monomer intercalation and in situ copolymerization.CHINESE SCIENCE BULLETIN,47(15),1267-1270. |
| MLA | Guo, CY,et al."Preparation of PE/MMT nanocomposite by monomer intercalation and in situ copolymerization".CHINESE SCIENCE BULLETIN 47.15(2002):1267-1270. |
入库方式： OAI收割
来源：化学研究所
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