Synthesis and characterization of a novel polyorganosiloxane having a bigger sized tubular structure and its supramolecular clathrate
文献类型：期刊论文
| 作者 | Liu, CQ; Liu, ZH; Xie, P; Dai, DR; Zhang, RB; Zhu, CF; Wang, C; He, CB; Chung, NTS |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2002-03-01 |
| 卷号 | 13期号:3-4页码:188-195 |
| 关键词 | Polyorganosiloxane Hydrosilylation Supramolecular Clathrate |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.171 |
| 英文摘要 | A novel polyorganosiloxane having a bigger sized tubular structure, tubular polymer (TP) was synthesized successfully by hydrosilylation reaction of reactive cis-isotactic ladder-like polyallylsilsesquioxane (Allyl-T) with coupling agent p-bis(dimethylhydrogensilyl)oxydiphenylene (M) in the presence of dicyclopentadienyl-platinum(II) chloride (Cp2PtCl2) catalyst. A novel supramolecular TP clathrate (TP/LC) was prepared by in situ encapsulating rod-like liquid crystalline molecule within the pore of TP. The Allyl-T was prepared by stepwise coupling polymerization. Various characterization methods including solubility test, FT-IR, H-1-NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), vapour pressure osmometer (VPO), X-ray diffraction (XRD), atomic force microscopy (AFM), polarized optical microscopy (POM) and molecular simulation were used and the results not only proved the existence of nano-scale tubular structures in the TP, but also demonstrated that a novel soluble supramolecular clathrate had been formed. Copyright (C) 2002 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174200300006 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78733]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC, Beijing 100080, Peoples R China 2.Natl Univ Singapore, Inst Mat Res & Engn, Singapore 11920, Singapore |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Liu, ZH,Xie, P,et al. Synthesis and characterization of a novel polyorganosiloxane having a bigger sized tubular structure and its supramolecular clathrate[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):188-195. |
| APA | Liu, CQ.,Liu, ZH.,Xie, P.,Dai, DR.,Zhang, RB.,...&Chung, NTS.(2002).Synthesis and characterization of a novel polyorganosiloxane having a bigger sized tubular structure and its supramolecular clathrate.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),188-195. |
| MLA | Liu, CQ,et al."Synthesis and characterization of a novel polyorganosiloxane having a bigger sized tubular structure and its supramolecular clathrate".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):188-195. |
入库方式： OAI收割
来源：化学研究所
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