Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts
文献类型：期刊论文
| 作者 | Yin, JB; Chen, XS; Zhang, L; Liu, A; Yang, YN; Yin, M; Lou, L |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2002-07-01 |
| 卷号 | 23期号:7页码:1363-1366 |
| 关键词 | Palladium Polymer Supported Catalyst Furfural Hydrogenation |
| ISSN号 | 0251-0790 |
| 英文摘要 | Three kinds of polymer resin supported Pd catalysts were prepared by mixing PdCl2, with alkaline styrene anion exchange resins[D392 -NH2, D382, -NHCH3, D301R, -NH(CH3)(2)], strongly alkaline styrene anion exchanged resin [201 X 7DVB, -NH+ (CH3)(3)] and alkaline epoxy exchange resin (701, -NH2), and hydrogenating in liquid phase at 1.013 X 10(5) Pa. The hydrogenation of furfural was studied under the reaction conditions such as solvent, temperature. Pd content in the supported catalyst and the amount of the catalyst. The yield of hydrogenation reaction of furfural markedly increased to 100% and the selectivity to tetrahydrofurfuryl alcohol increased to over 98% by polymer (alkaline styrene anion exchange resins D392, -NH2, D382, -NHCH3) supported palladium catalysts comparing with the yield over 70% and selectivity over 97% by palladium catalyst, in 50% alcohol-50% water or pure water solution at 1.013 X 10(5) Pa. The relationship between hydrogenation and the structures of functional group in the supporting resin was examined by XPS method. |
| 语种 | 英语 |
| WOS记录号 | WOS:000176908400036 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78797]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yin, JB |
| 作者单位 | 1.Jilin Inst Technol, Dept Chem Engn, Seoul 130012, South Korea 2.Chinese Acad Sci, Changchun Inst Appl Chem, China Petr Corp, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Union Lab Polymer Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, JB,Chen, XS,Zhang, L,et al. Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(7):1363-1366. |
| APA | Yin, JB.,Chen, XS.,Zhang, L.,Liu, A.,Yang, YN.,...&Lou, L.(2002).Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(7),1363-1366. |
| MLA | Yin, JB,et al."Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.7(2002):1363-1366. |
入库方式： OAI收割
来源：化学研究所
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