"Living"/controlled radical copolymerization of N-phenylmaleimide and styrene using Frechet-type dendritic initiators
文献类型：期刊论文
| 作者 | Zhao, YL; Jiang, J; Liu, HW; Chen, CF; Xi, F |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2002-04-01 |
| 卷号 | 45期号:2页码:135-142 |
| 关键词 | Dendritic-linear Block Copolymer Macroinitiator N-phenylmaleimide Styrene Atom Transfer Radical Copolymerization |
| ISSN号 | 1006-9291 |
| 英文摘要 | Polyarylether dendrons as macroinitiators for the "living"/controlled free radical copolymerization of N-phenylmaleimide (PhMI) and styrene (St) have been demonstrated. The copolymerization was carried out in bulk or anisole with CuBr/bipy catalyst at 100-130degreesC. It is found that the resulting copolymers possess predetermined molecular weights and narrower polydispersities (1.18 < M-w/M-n<1.32). The effects of reaction temperature and monomer feed on the copolymerization kinetics were investigated in detail. By using the Fineman-Ross method, the apparent monomer reactivity ratios for the atom transfer radical copolymerization of PhMI and St were determined to be r(PhMI) = 0.0207, and r(St) = 0.0484, respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:000175009000004 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78843]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, F |
| 作者单位 | Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, YL,Jiang, J,Liu, HW,et al. "Living"/controlled radical copolymerization of N-phenylmaleimide and styrene using Frechet-type dendritic initiators[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2002,45(2):135-142. |
| APA | Zhao, YL,Jiang, J,Liu, HW,Chen, CF,&Xi, F.(2002)."Living"/controlled radical copolymerization of N-phenylmaleimide and styrene using Frechet-type dendritic initiators.SCIENCE IN CHINA SERIES B-CHEMISTRY,45(2),135-142. |
| MLA | Zhao, YL,et al.""Living"/controlled radical copolymerization of N-phenylmaleimide and styrene using Frechet-type dendritic initiators".SCIENCE IN CHINA SERIES B-CHEMISTRY 45.2(2002):135-142. |
入库方式： OAI收割
来源：化学研究所
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