Synthesis and structure of a novel 18-Mo polyoxomolybdate
文献类型：期刊论文
| 作者 | Liu, G; Zhang, SW |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2002-07-01 |
| 卷号 | 18期号:7页码:624-628 |
| 关键词 | Molybdenum Polyoxomolybdate Girdle-like Structure Chain-like Structure Crystal Structure |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20020711 |
| 英文摘要 | A new compound (NH4)(6) (.) [Ca-2(H2O)(6)(CH3COO)(2)] (.) (Ca@ [(Mo10Mo8O52)-Mo-IV-O-V(OH)(4)(CH3COO)(2)]} (.) 14H(2)Owas prepared and the structure was determined by X-ray diffraction analysis. The compound shows an interesting girdle-like structure that is composed of eighteen Mo - O octahedra. There is a Ca2+ cation in the center of the girdle, which connects to the girdle backbone by bonding to four oxygen atoms of the girdle. The valences of ten Mo atoms are + 6 while those of the other eight Mo atoms are + 5, between which Mo - Mo bonds are found. Four acetic ligands connect to the girdle. The girdles link into ID chains by the Ca2+ cations above and below the girdle bonding to the backbone oxygen atoms. This compound is triclinic, space group P1, a = 1.0552(2)mn, b = 1.5150(3)nm, c = 1.5449(3)nm, alpha = 60.84(3), beta = 88.00(3), gamma = 71.21(3)degrees, V = 2.0194(7)nm, R-1 = 0.0366and wR(2) = 0.083. |
| 语种 | 英语 |
| WOS记录号 | WOS:000177048000011 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78865]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, SW |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, G,Zhang, SW. Synthesis and structure of a novel 18-Mo polyoxomolybdate[J]. ACTA PHYSICO-CHIMICA SINICA,2002,18(7):624-628. |
| APA | Liu, G,&Zhang, SW.(2002).Synthesis and structure of a novel 18-Mo polyoxomolybdate.ACTA PHYSICO-CHIMICA SINICA,18(7),624-628. |
| MLA | Liu, G,et al."Synthesis and structure of a novel 18-Mo polyoxomolybdate".ACTA PHYSICO-CHIMICA SINICA 18.7(2002):624-628. |
入库方式： OAI收割
来源：化学研究所
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