Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)
文献类型：期刊论文
| 作者 | Wang, XQ; Xu, D; Cheng, XF; Lu, MK; Yuan, DR; Huang, J; Lu, GW; Xie, TX; Wang, SL; Lu, GT |
| 刊名 | CRYSTAL RESEARCH AND TECHNOLOGY
 |
| 出版日期 | 2002 |
| 卷号 | 37期号:6页码:551-563 |
| 关键词 | Dcrystal Growth Mnhg(Scn)(4)(H2o)(2).2(C3h6conch3) Spectroscopic Characterizations Thermal Properties Optical Properties |
| ISSN号 | 0232-1300 |
| 英文摘要 | In this article, diaquatetrakis (thiocyanato) manganese(II) mercury (II)-N-methyl-2-pyrrolidone, MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3), (abbreviated as MMTWMP), a new organometallic nonlinear optical crystal material is reported. The structure, optical and thermal characterizations were determined by elemental analysis, infrared and Raman spectroscopy, X-ray powder diffraction, thermogravimetric analysis, differential scanning calorimetry, special heat, SHG measurements and UV/Vis/NIR optical transmission spectra. It belongs to the tetragonal crystallographic system, with cell parameters: a = 12.1294, c = 8.2238Angstrom, V = 1211.27Angstrom(3). Single crystals with dimensions up to 8 x 7 x 5 mm(3) have been obtained. The morphology of the crystals was indexed. The MMTWMP crystal exhibits good physicochemical stability at normal temperature and pressure. Its UV transparency cutoff is 360 run, which is shifted to the violet by 13 nm, as compared with MnHg(SCN), (MMTC), the optical transmission is 44.82% at 404 nm, which is by 17.46% higher than that of MMTC. |
| 语种 | 英语 |
| WOS记录号 | WOS:000176200200003 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/78979]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, XQ |
| 作者单位 | 1.Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Shandong Univ, Inst Modern Anal, Coll Environm Sci & Engn, Jinan 250100, Peoples R China 3.Shandong Univ, Dept Phys, Jinan 250100, Peoples R China 4.Petrol Univ, Lab Geochem & Lithosphere Dynam, Dongying 250765, Peoples R China 5.Chinese Acad Sci, Inst Chem, State Key Engn Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, XQ,Xu, D,Cheng, XF,et al. Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)[J]. CRYSTAL RESEARCH AND TECHNOLOGY,2002,37(6):551-563. |
| APA | Wang, XQ.,Xu, D.,Cheng, XF.,Lu, MK.,Yuan, DR.,...&Zhou, YQ.(2002).Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3).CRYSTAL RESEARCH AND TECHNOLOGY,37(6),551-563. |
| MLA | Wang, XQ,et al."Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)".CRYSTAL RESEARCH AND TECHNOLOGY 37.6(2002):551-563. |
入库方式： OAI收割
来源：化学研究所
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