Growth and characterization of a novel UV nonlinear optical crystal: [MnHg(SCN)(4)(H2O)(2)] center dot 2C(4)H(9)NO
文献类型:期刊论文
作者 | Wang, XQ; Xu, D; Lu, MK; Yuan, DR; Huang, J; Cheng, XF; Xie, TX; Zhang, GH; Wang, SL; Guo, SY |
刊名 | JOURNAL OF CRYSTAL GROWTH
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出版日期 | 2002 |
卷号 | 234期号:2-3页码:469-479 |
关键词 | Characterization Solvents X-ray Diffraction Growth From Solutions Single Crystal Growth Nonlinear Optic Materials |
ISSN号 | 0022-0248 |
英文摘要 | Single crystals of the organometallic nonlinear optical material, diaqua(thiocyanato) manganese(II)mercury(II)IN,N-dimethylacetamide (MMTWD), were grown from aqueous solutions. The morphology of the crystals was indexed. The grown crystals were characterized by elemental analyses, scanning electron microscopy (SEM), Raman and infrared spectroscopy, X-ray powder diffraction (XRPD), thermal analysis and Vis/UV/NIR spectroscopy. The MMTWD crystal exhibits good physicochemical stability at normal temperature and pressure. Its UV transparency cutoff is 360 nm, which is shifted to the violet by 13 nm, as compared with MnHg(SCN)(4) (MMTC). The optical transmission is 55.17% at 404 nm, which is by 27.81 % higher than that of MMTC. (C) 2002 Elsevier Science B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000173057500033 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/78983] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, XQ |
作者单位 | 1.Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Shandong Univ, Coll Environm Sci & Engn, Inst Modern Anal, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Inst Chem, Staate Key Engn Lab, Beijing 100080, Peoples R China 4.Analyt Soc Shandong Province, Jinan 250020, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, XQ,Xu, D,Lu, MK,et al. Growth and characterization of a novel UV nonlinear optical crystal: [MnHg(SCN)(4)(H2O)(2)] center dot 2C(4)H(9)NO[J]. JOURNAL OF CRYSTAL GROWTH,2002,234(2-3):469-479. |
APA | Wang, XQ.,Xu, D.,Lu, MK.,Yuan, DR.,Huang, J.,...&Wang, P.(2002).Growth and characterization of a novel UV nonlinear optical crystal: [MnHg(SCN)(4)(H2O)(2)] center dot 2C(4)H(9)NO.JOURNAL OF CRYSTAL GROWTH,234(2-3),469-479. |
MLA | Wang, XQ,et al."Growth and characterization of a novel UV nonlinear optical crystal: [MnHg(SCN)(4)(H2O)(2)] center dot 2C(4)H(9)NO".JOURNAL OF CRYSTAL GROWTH 234.2-3(2002):469-479. |
入库方式: OAI收割
来源:化学研究所
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