Synthesis and structure of polymethylsilsesquioxane-clay nanocomposite via in situ intercalative polymerization
文献类型：期刊论文
| 作者 | Ma, J; Shi, LH; Yang, MS; Li, BY; Liu, HY; Xu, J |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2002-12-27 |
| 卷号 | 86期号:14页码:3708-3711 |
| 关键词 | Nanocomposites Polymethylsilsesquioxane Intercalative Polymerization |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.11369 |
| 英文摘要 | Polymethylsilsesquioxane (PMSQ)-montmorillonite (MMT) nanocomposites were prepared by in situ intercalative polymerization. The dispersion of the MMT layers within the matrix was verified by X-ray diffraction and transmission electron microscopy, which revealed an intercalated morphology with layer spacing of 3.42 nm. The layer spacing was not increased after annealing at 150degreesC for 3 h. The reason for this result is explained in light of the molecular structure of PMSQ synthesized in and out of the nanoconfined environment. The coherent order of the silicate layer was decreased after the annealing, possibly because of the change in the PMSQ molecule during the annealing process. (C) 2002 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000179071100032 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79033]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, J |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, J,Shi, LH,Yang, MS,et al. Synthesis and structure of polymethylsilsesquioxane-clay nanocomposite via in situ intercalative polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2002,86(14):3708-3711. |
| APA | Ma, J,Shi, LH,Yang, MS,Li, BY,Liu, HY,&Xu, J.(2002).Synthesis and structure of polymethylsilsesquioxane-clay nanocomposite via in situ intercalative polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,86(14),3708-3711. |
| MLA | Ma, J,et al."Synthesis and structure of polymethylsilsesquioxane-clay nanocomposite via in situ intercalative polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 86.14(2002):3708-3711. |
入库方式： OAI收割
来源：化学研究所
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