Preparation of functionalized montmorillonites and their application in supported zirconocene catalysts for ethylene polymerization
文献类型：期刊论文
| 作者 | Liu, CB; Tang, T; Zhao, ZF; Huang, BT |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2002-06-01 |
| 卷号 | 40期号:11页码:1892-1898 |
| 关键词 | Functionalized Montmorillonite Zirconocene Zr Loading Ethylene Polymerization Activity Bulk Density Host-guest Systems Functionalized Montmorillorite Supports Zirconocene |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.10265 |
| 英文摘要 | Ethylene polymerization was carried out with zirconocene catalysts supported on montmorillonite (or functionalized montmorillonite). The functionalized montmorillonite was from simple ion exchange of [CH3O2CCH2NH3](+) (MeGlyH(+)) ions with interlamellar cations of layered montmorillonites. The functionalized montmorillonlites [high-purity montmorillonite (MMT)-MeGlyH(+)] had larger interlayer spacing (12.69 Angstrom) than montmorillonites without treatment (9.65 Angstrom). The zirconocene catalyst system [Cp2ZrCl2/methylaluminoxane (MAO)/MMT-MeGlyH(+)] had much higher Zr loading and higher activities than those of' other zirconocene catalyst systems (Cp2ZrCl2/MMT, Cp2ZrCl2/MMT-MeGlyH(+), Cp2ZrCl2/MAO/MMT, [CP2ZrCl](+)[BF4]/MMT, [Cp2ZrCl][BF4](-)/MMT-MeGlyH(+), [CP2ZrCl](+)[BF4](-)/MAO/MMT-MeGlyH(+), and [Cp2ZrCl](+)[BF4](-)/MAO/MMT). The polyethylenes with good bulk density were obtained from the catalyst systems, particularly (CP2ZrCl2/MAO/MMT-MeGlyH(1)). MeGlyH(+) and MAO seemed to play important roles for preparation of the supported zirconocenes and polymerization of ethylene. The difference in Zr loading and catalytic activity among the supported zirconocene catalysts is discussed. (C) 2002 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000175550700025 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79037]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CB,Tang, T,Zhao, ZF,et al. Preparation of functionalized montmorillonites and their application in supported zirconocene catalysts for ethylene polymerization[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2002,40(11):1892-1898. |
| APA | Liu, CB,Tang, T,Zhao, ZF,&Huang, BT.(2002).Preparation of functionalized montmorillonites and their application in supported zirconocene catalysts for ethylene polymerization.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,40(11),1892-1898. |
| MLA | Liu, CB,et al."Preparation of functionalized montmorillonites and their application in supported zirconocene catalysts for ethylene polymerization".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 40.11(2002):1892-1898. |
入库方式： OAI收割
来源：化学研究所
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