Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne
文献类型:期刊论文
作者 | Geng, JX; Geng, FX; Yang, XN; Wang, JK; Li, G; Zhou, E; Tang, BZ |
刊名 | MOLECULAR CRYSTALS AND LIQUID CRYSTALS
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出版日期 | 2002 |
卷号 | 383页码:115-130 |
关键词 | Acetylene Structure Morphology Tem |
ISSN号 | 1058-725X |
DOI | 10.1080/10587250290120378 |
英文摘要 | The crystal structure of 11-{[(4'-heptoxy-4-biphenylyl) carbonyl] oxy}-1-undecyne (A9EO7), an acetylene with a biphenyl mesogenic moiety, was studied by combination of electron diffraction (ED), wide-angle X-ray diffraction (WAXD), and molecular simulation of ED pattern and molecular packing. A9EO7 was found to adopt an orthorhombic P2(1)2(1)2 space group with cell parameters of a = 5.78 Angstrom, b = 7.46 Angstrom, and c = 63.26 Angstrom, for which molecular packing calculations were conducted to elucidate the molecular conformation. Its crystal morphology was observed using a transmission electron microscope (TEM) and an atom force microscope (AFM). A9EO7 crystal grew to form step like morphology. Crystallization behavior of A9EO7 in magnetic field was examined. Induced by magnetic field A9EO7 could crystallize in such a way that its molecular long axis was parallel to the substrate. |
语种 | 英语 |
WOS记录号 | WOS:000179440300009 |
出版者 | TAYLOR & FRANCIS LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/79039] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, G |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 | Geng, JX,Geng, FX,Yang, XN,et al. Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS,2002,383:115-130. |
APA | Geng, JX.,Geng, FX.,Yang, XN.,Wang, JK.,Li, G.,...&Tang, BZ.(2002).Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne.MOLECULAR CRYSTALS AND LIQUID CRYSTALS,383,115-130. |
MLA | Geng, JX,et al."Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne".MOLECULAR CRYSTALS AND LIQUID CRYSTALS 383(2002):115-130. |
入库方式: OAI收割
来源:化学研究所
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