中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne

文献类型:期刊论文

作者Geng, JX; Geng, FX; Yang, XN; Wang, JK; Li, G; Zhou, E; Tang, BZ
刊名MOLECULAR CRYSTALS AND LIQUID CRYSTALS
出版日期2002
卷号383页码:115-130
关键词Acetylene Structure Morphology Tem
ISSN号1058-725X
DOI10.1080/10587250290120378
英文摘要The crystal structure of 11-{[(4'-heptoxy-4-biphenylyl) carbonyl] oxy}-1-undecyne (A9EO7), an acetylene with a biphenyl mesogenic moiety, was studied by combination of electron diffraction (ED), wide-angle X-ray diffraction (WAXD), and molecular simulation of ED pattern and molecular packing. A9EO7 was found to adopt an orthorhombic P2(1)2(1)2 space group with cell parameters of a = 5.78 Angstrom, b = 7.46 Angstrom, and c = 63.26 Angstrom, for which molecular packing calculations were conducted to elucidate the molecular conformation. Its crystal morphology was observed using a transmission electron microscope (TEM) and an atom force microscope (AFM). A9EO7 crystal grew to form step like morphology. Crystallization behavior of A9EO7 in magnetic field was examined. Induced by magnetic field A9EO7 could crystallize in such a way that its molecular long axis was parallel to the substrate.
语种英语
WOS记录号WOS:000179440300009
出版者TAYLOR & FRANCIS LTD
源URL[http://ir.iccas.ac.cn/handle/121111/79039]  
专题中国科学院化学研究所
通讯作者Li, G
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
推荐引用方式
GB/T 7714
Geng, JX,Geng, FX,Yang, XN,et al. Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS,2002,383:115-130.
APA Geng, JX.,Geng, FX.,Yang, XN.,Wang, JK.,Li, G.,...&Tang, BZ.(2002).Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne.MOLECULAR CRYSTALS AND LIQUID CRYSTALS,383,115-130.
MLA Geng, JX,et al."Crystal structure of 11-{[(4 '-heptoxy-4-biphenylyl) carbonyl]oxy}-1-undecyne".MOLECULAR CRYSTALS AND LIQUID CRYSTALS 383(2002):115-130.

入库方式: OAI收割

来源:化学研究所

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