Crystallization and morphology of poly(ethylene-2,6-naphthalene dicarboxylate) in the presence of nucleating agents
文献类型：期刊论文
| 作者 | Gao, X; Lu, RG; Jin, MN; Bu, HS |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2002-10-15 |
| 卷号 | 40期号:20页码:2387-2394 |
| 关键词 | Nucleation Nucleating Agent Crystallization Morphology Poly(Ethylene-2 6-naphthalene Dicarboxylate) |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.10296 |
| 英文摘要 | The crystallization and morphology of poly(ethylene-2,6-naphthalene dicarboxylate) (PEN) containing, as nucleating agents, a sodium salt of a copolymer of ethylene and acrylic acid or a sodium salt of a copolymer of ethylene and methacrylic acid, were investigated with differential scanning calorimetry, polarized optical microscopy, and small-angle light scattering. The nucleating agents accelerated the crystallization rate at high temperatures by decreasing the surface free energy barrier hindering nucleation. Meanwhile, the nucleating agents with flexible chains could also improve the mobility of the PEN chains and increase the crystallization rate at low temperatures. Hedrites were observed when PEN was crystallized at high temperatures, whereas crystallization at low temperatures led to the formation of spherulites. Similar but smaller morphologies were obtained in the presence of nucleating agents. With nucleating agents, the spherulites formed at low temperatures were less perfect, although the optical properties of the spherulites were not influenced. (C) 2002 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000178180700005 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79129]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bu, HS |
| 作者单位 | 1.Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, X,Lu, RG,Jin, MN,et al. Crystallization and morphology of poly(ethylene-2,6-naphthalene dicarboxylate) in the presence of nucleating agents[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2002,40(20):2387-2394. |
| APA | Gao, X,Lu, RG,Jin, MN,&Bu, HS.(2002).Crystallization and morphology of poly(ethylene-2,6-naphthalene dicarboxylate) in the presence of nucleating agents.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,40(20),2387-2394. |
| MLA | Gao, X,et al."Crystallization and morphology of poly(ethylene-2,6-naphthalene dicarboxylate) in the presence of nucleating agents".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 40.20(2002):2387-2394. |
入库方式： OAI收割
来源：化学研究所
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