Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene
文献类型：期刊论文
| 作者 | Zhao, YL; Li, HM; Liu, PS; Liu, HW; Jiang, J; Xi, F |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2002-04-01 |
| 卷号 | 83期号:14页码:3007-3012 |
| 关键词 | N-butyl Maleimide Styrene Charge-transfer Complex Solution Copolymerization Reactivity Ratios |
| ISSN号 | 0021-8995 |
| 英文摘要 | As for the charge-transfer complex (CTC) formed by N-butyl maleimide (NMBI) and styrene in chloroform, the complex formation constant was determined by H-1-NMR of Hanna-Ashbaugh. The copolymerization of NBMI (NBMI, M-1) and styrene (St, M-2) in chloroform using AIBN as an initiator was investigated. On the basis of the kinetic model proposed by Shan, the reactivity ratios of free monomers and CTC in the copolymerization were calculated to be r(12) = 0.0440, r(21) = 0.0349, r(1C) = 0.00688, r(2C) = 0.00476, and the ratios of rate constants were obtained to be k(1C)/k(12) = 6.40, k(2C)/k(21) = 7.33. In addition, the copolymer was characterized by IR, H-1-NMR, DSC, and TGA. (C) 2002 John Wiley Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173534600007 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79283]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, F |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Xiangtan Univ, Coll Chem & Chem Engn, Xiangtan 411105, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, YL,Li, HM,Liu, PS,et al. Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2002,83(14):3007-3012. |
| APA | Zhao, YL,Li, HM,Liu, PS,Liu, HW,Jiang, J,&Xi, F.(2002).Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene.JOURNAL OF APPLIED POLYMER SCIENCE,83(14),3007-3012. |
| MLA | Zhao, YL,et al."Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene".JOURNAL OF APPLIED POLYMER SCIENCE 83.14(2002):3007-3012. |
入库方式： OAI收割
来源：化学研究所
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