The beheavior of ethylene oligomerization catalized by a novel late metal-transition catalyst
文献类型：期刊论文
| 作者 | Jiang, T; Yan, WD; Wang, H; Liu, BB; Xu, WQ; Ma, JJ; Hu, YL |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2002-06-01 |
| 期号 | 3页码:293-296 |
| 关键词 | Ethylene Oligomerization Late Transition Metal Catalyst Alpha-olefin Kinetics |
| ISSN号 | 1000-3304 |
| 英文摘要 | A new late metal-transition complex {[(2-ArN=C(Me))(2)-C5H3N]FeCl2\Ar = 2,4-C6H4(CH3)(2)} was designed and synthesized. The behavior of ethylene oligomenization catalyzed by this complex with NIAO as cocatalyst has been studied. The effects of temperature, Al/Fe molar ratio, the concentration of catalyst and ethylene pressure on the catalytic activity and the rate of oligomerization were investigated. It was found that the catalyst is characterized by its high activity (the maximum is up to 4.25 x 10(8) g oligomer/molFe.h at 30degreesC, and 3.0 MPa) and high initial reaction rate. The kinetic curves obtained is of decay type. |
| 语种 | 英语 |
| WOS记录号 | WOS:000176694400007 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79285]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, T |
| 作者单位 | 1.Chinese Acad Sci, Ctr Mol, Inst Chem, State Key Lab Plast, Beijing 100080, Peoples R China 2.Hebei Univ Technol, Dept Chem & Engn, Inst Polymer Sci & Engn, Tianjin 300130, Peoples R China 3.Dushanzi Petrochem Co, PetroChina, Res Inst, Dushanzi 833600, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, T,Yan, WD,Wang, H,et al. The beheavior of ethylene oligomerization catalized by a novel late metal-transition catalyst[J]. ACTA POLYMERICA SINICA,2002(3):293-296. |
| APA | Jiang, T.,Yan, WD.,Wang, H.,Liu, BB.,Xu, WQ.,...&Hu, YL.(2002).The beheavior of ethylene oligomerization catalized by a novel late metal-transition catalyst.ACTA POLYMERICA SINICA(3),293-296. |
| MLA | Jiang, T,et al."The beheavior of ethylene oligomerization catalized by a novel late metal-transition catalyst".ACTA POLYMERICA SINICA .3(2002):293-296. |
入库方式： OAI收割
来源：化学研究所
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