Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands
文献类型：期刊论文
| 作者 | Yu, XY; Jin, GX; Weng, LH |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2002-11-01 |
| 卷号 | 20期号:11页码:1256-1262 |
| 关键词 | Lanthanocene Complex Crystal Structure Dichalcogenolate O-carborane Metathesis Reaction |
| ISSN号 | 1001-604X |
| 英文摘要 | Reactions of [ Cp(2)Ln(mu-Cl)](2) (Cp = eta(5)-C5H5, Ln = Nd, Yb, Dy, Gd, Er) with an equivalent of [ (THF)(3)LiE2C2B10H10Li. (TT-IF) (THF)](2) (E = S, Se) in THF afforded the dinuclear sandwich complexes of formula[Cp(2)LnE(2)C(2)B(10)H(10)](2)[Li(THF)(4)](2) [E = S, Ln = Nd (1a), Yb (2a), Dy (3a), Gd (4a), Er (5a); E = Se, Ln = Nd (1b), Yb (2b), Dy (3b), Gd (4b), Er (5b)]. The molecular structures of complexes la, 2a and 2b were determined by the single crystal X-ray structure analyses. Two lanthanide atoms are connected by a pair chalcogen (eta(1), eta(2)-E2C2B10H10) bridging ligands and the central Ln(2)E(2) four membered ring is not planar. |
| 语种 | 英语 |
| WOS记录号 | WOS:000179210800018 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79295]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jin, GX |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Fudan Univ, Dept Chem, Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, XY,Jin, GX,Weng, LH. Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(11):1256-1262. |
| APA | Yu, XY,Jin, GX,&Weng, LH.(2002).Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands.CHINESE JOURNAL OF CHEMISTRY,20(11),1256-1262. |
| MLA | Yu, XY,et al."Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands".CHINESE JOURNAL OF CHEMISTRY 20.11(2002):1256-1262. |
入库方式： OAI收割
来源：化学研究所
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