Synthesis and properties of poly-2-aminopyridine
文献类型：期刊论文
| 作者 | Kan, JQ; Li, X; Li, YF |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2002-02-01 |
| 卷号 | 18期号:2页码:106-111 |
| 关键词 | 2-aminopyridine Electrochemical Polymerization Cyclic Voltammetry Poly-2-aminopyridine Partical Size |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20020203 |
| 英文摘要 | Poly-2-aminopyridine was synthesized using potential cycling in the solution of 0.43 mol (.) dm(-3) 2-aminopyridine and 0.01 mol (.) dm(-3) NaOH. There are three pairs of redox peaks on the cyclic voltammogram of poly-2-aminopyridine in the solution of 1.0 mol (.) dm(-3) ZnCl2 (pH = 4.99). The experiments of rotating ring-disk electrode (RRDE) indicate that an intermediate is generated in the initiation of polymerization. The IR spectra indicate that poly-2-aminopyridine has head-to-tail structure. According to the results of atom force microscope the average particle size of poly-2-aminopyridine is about 893.4 run, and the average distance between particles is about 255 nm. The discharge behavior of the battery consisting poly-2-aminopyridine as cathode, and zinc as anode in an electrolytic solution of 2.5 mol (.) dm(-3) ZnCl2 + 3.0 mol (.) dm(-3) NH4Cl (pH = 5.5) is very similar to that of the battery of Li-SOCl2. The discharge curve is very flat in the middle region. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173613600003 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79329]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kan, JQ |
| 作者单位 | 1.Yangzhou Univ, Sch Sci, Dept Chem, Yangzhou 225002, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kan, JQ,Li, X,Li, YF. Synthesis and properties of poly-2-aminopyridine[J]. ACTA PHYSICO-CHIMICA SINICA,2002,18(2):106-111. |
| APA | Kan, JQ,Li, X,&Li, YF.(2002).Synthesis and properties of poly-2-aminopyridine.ACTA PHYSICO-CHIMICA SINICA,18(2),106-111. |
| MLA | Kan, JQ,et al."Synthesis and properties of poly-2-aminopyridine".ACTA PHYSICO-CHIMICA SINICA 18.2(2002):106-111. |
入库方式： OAI收割
来源：化学研究所
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