Synthesis and characterization of nylon 1012/clay nanocomposite
文献类型：期刊论文
| 作者 | Wu, ZG; Zhou, CX; Qi, RR; Zhang, HB |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2002-03-14 |
| 卷号 | 83期号:11页码:2403-2410 |
| 关键词 | Nanocomposite Nylon 1012 Melt Polycondensation Polymerization Clay Exfoliation |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.10198 |
| 英文摘要 | A nylon 1012/clay nanocomposite was prepared by melt polycondensation polymerization of diamine and diacid in the presence of organoclay. The nylon 1012 and nanocomposite were characterized by Fourier transform IR spectroscopy with attenuated total reflection, and a shift of the Si-O-Si band toward a lower wavenumber was found as the result of the strong interaction of nylon 1012 with the organoclay. The X-ray diffraction analysis and transmission electron microscopy observation showed that the clay minerals were exfoliated. Clay platelets increased the crystallization rate but decreased the crystallinity. Differential scanning calorimetry and dynamic mechanical thermal analysis measurements showed that the glass-transition temperature of the nylon 1012/clay nanocomposite decreased to some degree as compared to nylon 1012 because of the combined effect of confinement and the reduction of the physical crosslink density. The mechanical properties of the nanocomposite such as the tensile strength and tensile modulus are higher than those of nylon 1012, and the water absorption is reduced because of the improvement in the barrier property of the nanocomposite. (C) 2002 John Wiley Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173214600016 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79503]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, CX |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Coll Chem & Chem Technol, Shanghai 200240, Peoples R China 2.Jilin Univ, State Key Lab Polymer Phys & Chem, Dept Chem, Changchun, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, ZG,Zhou, CX,Qi, RR,et al. Synthesis and characterization of nylon 1012/clay nanocomposite[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2002,83(11):2403-2410. |
| APA | Wu, ZG,Zhou, CX,Qi, RR,&Zhang, HB.(2002).Synthesis and characterization of nylon 1012/clay nanocomposite.JOURNAL OF APPLIED POLYMER SCIENCE,83(11),2403-2410. |
| MLA | Wu, ZG,et al."Synthesis and characterization of nylon 1012/clay nanocomposite".JOURNAL OF APPLIED POLYMER SCIENCE 83.11(2002):2403-2410. |
入库方式： OAI收割
来源：化学研究所
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