Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex
文献类型：期刊论文
| 作者 | Zhang, X; Han, B; Hua, YN; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2002-03-01 |
| 卷号 | 13期号:3-4页码:216-219 |
| 关键词 | Natural Biopolymer Casein-co Complex Chiral Catalyst Asymmetric Epoxidation (2r 3r)-(+)-3-phenylglycidol |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.176 |
| 英文摘要 | Silica-supported casein-Co complex (Si-CA-Co) was prepared from silica, casein and cobalt chloride, and found to be useful as a chiral catalyst for the asymmetric epoxidation 01 cinnamyl alcohol to (2R,3R)-(+)-3-phenylglycidol at 70degreesC and under I atmospheric oxygen pressure. When a proper content of cobalt in the Si-CA-Co complex and suitable reaction conditions were selected, the product and optical yield could be amounted to 70.6 and 92.0%, respectively, and the Si-CA-Co complex could be reused several times without any remarkable change in the optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000174200300011 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/79517]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, B |
| 作者单位 | Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, X,Han, B,Hua, YN,et al. Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):216-219. |
| APA | Zhang, X,Han, B,Hua, YN,Huang, MY,&Jiang, YY.(2002).Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),216-219. |
| MLA | Zhang, X,et al."Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):216-219. |
入库方式： OAI收割
来源：化学研究所
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